Alkenes
Mostrando 1-12 de 93 artigos, teses e dissertações.
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1. Thermal and Catalytic Fast Pyrolysis of Oily Extracts of Microalgae: Production of Biokerosene
Three different microalgae species, Desmodesmus sp., Nannochloropsis oculata and Halamphora coffeaeformis were grown under controlled conditions. The resulting dry biomass was characterized by TG-DTA (thermogravimetry-differential thermal analysis) and extracted with three solvents having different polarities. The extracts gross mass yields varied from 2% us
J. Braz. Chem. Soc.. Publicado em: 2021-04
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2. Catalytic Cracking of Soybean Oil for Biofuel over γ-Al2O3/CaO Composite Catalyst
In this paper, we report the catalytic cracking of soybean oil for biofuel over γ-Al2O3/CaO composite catalysts. The influence of catalysts, cracking temperature and weight hourly space velocity (WHSV) on the products distribution were investigated. The maximum yield (70.0 wt.%) of biofuel with low acid value (6.7 mg KOH g-1) and oxygen content (5.6%), as w
J. Braz. Chem. Soc.. Publicado em: 2019-02
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3. Ultrasound-Promoted Chemoselective Oxysulfonylation of Alkenes
The ultrasound-assisted oxysulfonylation of different alkenes using sodium salts of organosulfinic acids under air atmosphere is described. The reaction is chemo- and regioselective and the corresponding β-keto-sulfones were obtained in good yields as major products. The use of ultrasound greatly accelerated the formation of products when compared to the co
J. Braz. Chem. Soc.. Publicado em: 2018-06
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4. AVANÇOS RECENTES NA HIDROAMINAÇÃO DE COMPOSTOS INSATURADOS
This review presents thermodynamics and kinetics aspects of the hydroamination reaction, recent advancements on this field for non-activated alkenes, alkynes and allenes, employing transition metal catalysis or organocatalysis, including activation by hydrogen bonding or Brønsted acids. Selected syntheses that contain a strategic hydroamination step will be
Quím. Nova. Publicado em: 2017-09
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5. Variation of cuticular chemical compounds in three species of Mischocyttarus (Hymenoptera: Vespidae) eusocial wasps
Abstract The social wasps have a remarkable system of organization in which chemical communication mediate different behavioral interactions. Among the compounds involved in this process, cuticular hydrocarbons are considered the main signals for nestmate recognition, caste differentiation, and fertility communication. The aims of this study were to describe
Rev. Bras. entomol.. Publicado em: 2017-09
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6. Iodine(III)-Mediated Ring Contraction Reactions: Synthesis of Oxygen- and Nitrogen-Substituted Indanes
The synthesis of oxygen- and nitrogen-substituted indanes was successfully performed by iodine(III)-mediated ring contraction of 1,2-dihydronaphthalenes. Acetoxy and benzoyloxy alkenes afforded indanes in 60-71% yield, irrespective of their position on aromatic ring. Similarly, the nitrogen containing substrates protected with 9-fluorenylmethyloxycarbonyl (F
J. Braz. Chem. Soc.. Publicado em: 2016-10
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7. Upgrade of Biofuels Obtained from Waste Fish Oil Pyrolysis by Reactive Distillation
Bio-oil is classified as second-generation biofuel and it is produced mainly through the pyrolysis of a waste lignocellulosic biomass base. The application of this product is still very limited, due to some of its chemical characteristics. This paper presents a proposal for the reduction of the acidity of bio-oil obtained from waste fish oil, previously prod
J. Braz. Chem. Soc.. Publicado em: 2015-02
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8. Metabolite profiling of Schizochytrium sp. by GC-MS, an oleaginous microbial source of biodiesel
The chemical screening carried out on Schizochytrium sp. biomass led the identification of 24 types of organic compounds belonging to n-alkanes, 1-alkenes, 1-alkanols, free fatty acids, methyl and ethyl esters of saturated and unsaturated fatty acids, saturated tri- and diglycerides, unsaturated monoglycerides, wax esters, sterols, triterpenes, and mono- and
Braz. J. Microbiol.. Publicado em: 2014-06
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9. QSAR models of reaction rate constants of alkenes with ozone and hydroxyl radical
As constantes de velocidade da reação do ozônio com 95 alcenos (-logkO3) e do radical hidroxila (•OH) com 98 alcenos (-logkOH) na atmosfera foram previstas por modelos de relações quantitativas entre estrutura e atividade (QSAR). Cálculos usando a teoria do funcional da densidade (DFT) foram realizados para os respectivos alcenos no estado fundamenta
J. Braz. Chem. Soc.. Publicado em: 2013-11
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10. Factors influencing crude oil biodegradation by Yarrowia lipolytica
Yarrowia lipolytica is unique strictly aerobic yeast with the ability to efficiently degrade hydrophobic substrates such as n-alkenes, fatty acids, glycerol and oils. In the present work, a 2(4) full factorial design was used to investigate the influence of the independent variables of temperature, agitation, initial cell concentration and initial petroleum
Braz. arch. biol. technol.. Publicado em: 2012-10
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11. Dichloroiodoisocyanuric acid: a new reagent for regioselective coiodination of alkenes and iodination of activated arenes
O ácido dicloro-iodo-isocianúrico foi preparado em 93% de rendimento através do aquecimento do ácido tricloro-isocianúrico com 1,05 equiv. mol de iodo. Esse novo reagente se mostrou bastante eficiente para a iodação regiosseletiva de arenos ativados. Os alquenos reagem com o ácido dicloro-iodo-isocianúrico na presença de solventes nucleofílicos ox
Journal of the Brazilian Chemical Society. Publicado em: 2012-02
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12. Estudo da Aplicação de Brometo de Índio(I) em Reações para Formação de Ligações Carbono-Carbono / Studies on the Application of Indium(I) Bromide in Carbon-Carbon
This PhD thesis describes our results on the application of indium(I) bromide in carbon-carbon bond forming reactions. Indium enolates, generated in situ from the reaction between indium(I) bromide and α,α-dichloroketones, react with carbonyl compounds and electron-deficient alkenes. Reactions of indium enolate with α,α-dichloroketones, i
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 01/03/2011