Aplicações do espalhamento Raman no estudo de transições ferroeletricas em cristais com estrutura do tipo KDP

AUTOR(ES)
DATA DE PUBLICAÇÃO

1976

RESUMO

The low frequency Raman scattering in KDP, RDP and RDA in y(xy)x configuration has been investigated as a function of temperature with particular emphasis near the transition temperature TC. The spectra in the region of the overdamped and A-BO4 stretching modes have been fitted to the response function of two coupled damped hamonic oscillators and that of lattice oscillators due to Silverman. In both t.he formalisms, assuming purely real or purely imaginary coupling the overdamped mode softens with temperature well above TC but attains a "hard core" frequency near the phase transition. These results do not indicate existence of a mode approaching zero frequency in contrast to the earlier work by various authors

ASSUNTO(S)

efeito de espalhamento (fisica) raman cristais ferroeletricos

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