Canonical formulation of linkage thermodynamics.
AUTOR(ES)
Di Cera, E
RESUMO
The canonical structure of the group of thermodynamic potentials obtained from the energy of a physico-chemical system removes any possible distinction between physical and chemical binding phenomena. Transformations of these potentials by means of Jacobians give linkage relations for equilibrium thermodynamics. Linkage matrices are introduced to explore the functional properties of a biological macromolecule. They provide a quantitative basis for a broader approach and understanding of generalized binding phenomena.
ACESSO AO ARTIGO
http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=281691Documentos Relacionados
- Global and local metric geometry of ligand binding thermodynamics.
- "Adaptive" behavior of ligand-gated ion channels: constraints by thermodynamics.
- Transcription of ground-state density-functional theory into a local thermodynamics.
- Persistent confusion of total entropy and chemical system entropy in chemical thermodynamics.
- A high throughput method to investigate oligodeoxyribonucleotide hybridization kinetics and thermodynamics.