Driving force and nucleophilicity in SN2 displacements
AUTOR(ES)
Streitwieser, Andrew
RESUMO
The free energies of activation for reaction of six anionic nucleophiles with methyl iodide in dimethylformamide correlate linearly with the overall heats of reaction in the gas phase. The result indicates that nucleophilicity in this SN2 displacement reaction is dominated by electron affinity and bond-strength effects.
ACESSO AO ARTIGO
http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=390900Documentos Relacionados
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