Electron affinity of the methyl radical: Structures of CH3 and CH3-
AUTOR(ES)
Marynick, Dennis S.
RESUMO
Ab initio self-consistent field and configuration interaction calculations are presented for the methyl radical and anion. The methyl radical is shown to be planar (D3h), while the anion is pyramidal (C3v). The methyl anion is unstable with respect to the limit of CH3 plus an electron by 2-8 kcal/mole. Potential curves for the out-of-plane bending motions of both molecules are presented.
ACESSO AO ARTIGO
http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=392297Documentos Relacionados
- Water sorption of CH3- and CF3-Bis-GMA based resins with additives
- Adhesion of Streptococcus sanguis CH3 to polymers with different surface free energies.
- Isolation and identification of a biologically active peptide derived from the CH3 domain of human IgG1.
- Kinetics of adhesion of the oral bacterium Streptococcus sanguis CH3 to polymers with different surface free energies.
- Behaviorismo radical: crítica e metacrítica