Flexible, Large-Area Organic Solar Cells With Improved Performance Through Incorporation of CoFe2O4 Nanoparticles in the Active Layer
AUTOR(ES)
Pereira, Maurício de Sousa
FONTE
Mat. Res.
DATA DE PUBLICAÇÃO
13/01/2020
RESUMO
Cobalt ferrite (CoFe2O4) nanoparticles (NPs), with an average diameter of about 4-10 nm, were produced by the proteic sol-gel method and successfully doped into the active layer of poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) organic solar cells. Pristine and CoFe2O4 NPs-doped blends of P3HT:PCBM were dispersed in a mixture of o-xylene:tetralin (1 mg/mL) based non-halogenated solvents and deposited via a semi-industrial blade coating process on flexible substrates to fabricate large area (0.55 cm2), flexible organic solar cells with inverted configuration. The main focus of this study aims to assess the influence of NPs on the efficiency, stability and lifetime of the produced devices. From the photovoltaic parameters it was observed that the optimization of the bulk-heterojunction through the incorporation of CoFe2O4 NPs resulted in increased short-circuit current density. As a result, the power conversion efficiency of doped devices increased by 10 % when compared with the undoped reference devices. Tests of lifetime and stability were performed using International Summit on OPV Stability (ISOS) protocols ISOS-D-3, ISOS-O-1 and ISOS-L-1. For the duration of the tests (1200 h), the results showed that doped cells presented performances at least comparable with those of reference cells.
Documentos Relacionados
- Gold Supported on Strontium Surface-Enriched CoFe2O4 Nanoparticles: a Strategy for the Selective Oxidation of Benzyl Alcohol
- Catalytic Ozonation of Melanoidin in Aqueous Solution over CoFe2O4 Catalyst
- Sinterização ultra-rápida de pós submicrométricos de CoFe2O4 por micro-ondas
- Al and PEG Effect on Structural and Physicochemical Properties of CoFe2O4
- Propriedades eletromagnéticas de amostras policristalinas de CoFe2O4 na faixa de RF e microondas.