Periodic explosions by positive feedback in a rising foam column

AUTOR(ES)

Zener, Clarence

RESUMO

An aqueous foam rising adiabatically in a column suffers a drop in temperature. Under appropriate conditions, such a column periodically explodes. We here trace this explosion to the tight thermal coupling between the foam and its enclosing glass column. When the surface surfactant concentration is unbuffered by micelles, a positive feedback exists between the flow of heat from the walls into the foam and the thermal conductivity of the foam itself. In our highly expanded foam, heat is conducted through the foam cells' interior primarily by the heat-pipe effect. Such an effect is retarded by a dense layer of surfactant molecules. Heat absorption causes cell expansion, which, in a foam unbuffered by micelles, causes a reduction in surface concentration of surfactant molecules and, hence, in an increase in thermal conductivity. This interpretation of our observed periodic explosions is in agreement with all of our observations.

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