Probing the transition state via photoelectron and photodetachment spectroscopy of H3O−
AUTOR(ES)
Zhang, Dong H.
FONTE
The National Academy of Sciences
RESUMO
The H3O− anion has stable and metastable structures that resemble configurations in the vicinity of the transition state for the neutral reactions OH + H2 ↔ H2O + H. Photoelectron spectroscopy of this anion probes the neutral reaction dynamics in the critical transition-state region. Accurate quantum dynamics calculations of the photoelectron intensity and photodissociation product energies are shown to provide a quantitatively reliable means of interpreting such experimental observations and reveal a detailed picture of the reaction dynamics.
ACESSO AO ARTIGO
http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=129311Documentos Relacionados
- Detailed electronic description of triple bonds between transition metal atoms and verification by photoelectron spectroscopy
- Infrared spectroscopy and X-ray diffraction study of complexes of histones H3 and H4 in the condensed state.
- X-ray photoelectron spectroscopy and infrared spectroscopy study of maleimide-activated supports for immobilization of oligodeoxyribonucleotides
- Evaluation of the Oxidation Degradation Process of Biodiesel via 1H NMR Spectroscopy
- A Comparative Analysis of BaTiO3/(Ba,Sr)TiO3 and BaTiO3/(Ba,Sr)TiO3/SrTiO3 Artificial Superlattices via Raman Spectroscopy
