Synthesis of new BLnZT nanostructured ferroelectric thin films
AUTOR(ES)
Ostos, Carlos, Martínez-Sarrión, Maria L., Mestres, Lourdes, Cortés, Alexander, Delgado, Eduardo, Prieto, Pedro
FONTE
Brazilian Journal of Physics
DATA DE PUBLICAÇÃO
2006-09
RESUMO
A novel synthesis method was employed to obtain a new family of lead-free compounds with the general formula: Ba1-yLn2y / 3Ti0.91Zr0.09O3 (Ln= lanthanide element). The thin films were deposited by RF-magnetron sputtering under high-oxygen pressure on different substrates at 873 K. The crystalline phases were studied via x-ray diffraction, showing the 001 epitaxial reflections corresponding to perovskite single-phase compounds. The films revealed high homogeneity and stoichiometries corresponding to BLnZT (Ln=Nd, La). Deposited thin films showed a smooth surface. Ferroelectric measurements through hysteresis curves were obtained in Ba0.90La0.067�0.033Ti0.91Zr0.09O3, capacitor structures showing clear ferroelectric behavior with Pr, Ps and Ec of 11.9 µC/cm², 36.8 µC/cm² and 38.6 kV/cm, respectively.
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