Bifunctional Catalysts
Mostrando 1-12 de 12 artigos, teses e dissertações.
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1. Isomerização do n-Hexano por platina suportada na zeólita H-ZSM-5 : efeito do teor de alumínio
O objetivo deste estudo foi verificar a influência da razão Si/Al (11,5, 15,0, 25,0, 40,0 e 140,0) na zeólita ZSM-5 através da conversão, atividade, seletividade e estabilidade de catalisadores bifuncionais (Pt/H-ZSM-5) aplicados a reação de isomerização do n-hexano. Para preparar os catalisadores bifuncionais, inicialmente as zeólitas foram submet
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 01/08/2011
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2. Bimetallic Pt-Ni catalysts supported on usy zeolite for n-hexane isomerization
Isomerization of linear alkanes has had considerable importance for the refining industry because the isomers formed in this reaction have high octane number. Most works reported in the literature studied the use of bifunctional catalysts, i.e., ones that have acid sites and metallic sites. In this study, bifunctional monometallic (Ni or Pt) and bimetallic c
Brazilian Journal of Chemical Engineering. Publicado em: 2009-06
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3. Eletrocatalisadores de ligas de platina dispersos em substratos de óxidos para a reação de oxidação de hidrogênio puro e na presença de CO / Electrocatalysts of platinum alloys dispersed in oxide substrates for pure hydrogen oxidation reaction and in the presence of CO
This work shows results of studies of the hydrogen oxidation reaction (HOR) pure in rotation in ultra porous layer and in the presence of CO in the fuel cell to the electrocatalysts of Pt alloy dispersed on oxide substrates such Pt/RuO 2 -C, Pt/RhO 2 -C, Pt/WO 3 -C, Pt/WC-C and pure materials, as RhO 2 /C and WC. The study of the catalytic properties of thes
Publicado em: 2009
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4. Efeito da concentração de irídio sobre as propriedades de catalisadores do tipo Pt-Ge-Ir/Al2O3. / Effect of concentration of iridium on the properties of type catalysts Pt-Ge-Ir/Al2O3.
The effect of iridium content on the activity, selectivity and stability of platinum, germanium and iridium supported in alumina catalysts for oil naphta catalytic reforming was studied in this work. Samples were prepared by the impregnation of the metallic salts (hexachloroplatinic acid, hexachoroiridic acid and germanium chloride) over g-alumina in order t
Publicado em: 2008
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5. Desenvolvimento de catalisadores bifuncionais de óxido de zircônio modificado por óxidos de tungstênio e molibdênio contendo platina para a reação de isomerização de n-parafinas / Development of bifunctional catalysts on zircon oxide modify by tungsten and molybdenum oxides contain platinum for nparaffin isomerization
Bifunctional catalysts based on zircon oxide modified by tungsten (W = 10, 15 and 20 %) and by molybdenum oxide (Mo= 10, 15 e 20 %) containg platinum (Pt = 1%) were prepared by the polymeric precursor method. For comparison, catalysts the tungsten base was also prepared by the impregnation method. After calcinations at 600, 700 and 800 C, the catalysts were
Publicado em: 2007
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6. Influência de M/C (M = Mo, Cu, Fe e W) incorporado à camada difusora do eletrodo de difusão de gás frente à reação de oxidação de hidrogênio na presença de CO
The performance of proton exchange membrane fuel cells (PEMFC) with Pt-based anodes is drastically lowered when CO-containing hydrogen is used to feed the system, because of the strong adsorption of CO on platinum. In the present work the effects of the presence of a conversion layer of CO to CO2 composed by several M/C materials (where M = Mo, Cu, Fe and W)
Química Nova. Publicado em: 2007
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7. Isomerização de n-hexano sobre Pt-NiHUSY empregando zeolita com alto teor de Al.
The isomerization reactions of linear alkanes are very important to petrochemical industries due to the isomer products in reaction possess high octane number. The majority of the literature articles involves the job of bifunctional catalysts, in the other words, catalysts containing acid sites and metallic sites. In this work, monometallic (Ni or Pt) and bi
Publicado em: 2005
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8. BASED BIFUNCTIONAL CATALYSTS IN ZEOLITE H-FERRIERITE FOR THE DIRECT SYNTHESIS OF DIMETHYL ETHER FROM SYNTHESIS GAS / CATALISADORES BIFUNCIONAIS BASEADOS EM ZEÓLITA H-FERRIERITA PARA A SÍNTESE DIRETA DE DIMETIL ÉTER A PARTIR DE GÁS DE SÍNTESE
The direct synthesis of dimethyl ether from syngas is catalyzed by bifunctional catalysts: the hydrogenation function that catalyzes the methanol formation and the dehydration function to produce dimethyl ether from methanol. Bifunctional catalysts with Cu, Zn and Al as hydrogenation component and Hferrierite zeolite as dehydration component had been synthes
Publicado em: 2004
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9. Evaluación de la estructura porosa de los materiales MCM-22, MCM-36 e ITQ-2 empleando el test catalitico del n-decano
The void structure of zeolites MCM-22, MCM-36 and ITQ-2 were discussed on the bases of catalytic reaction tests. The hydromerization of n-decane on bifunctional Pt/Zeolite Catalysts have been used as model reactions. Beta and ZSM-5 zeolites were used for comparison. It is concluded that all materials show features of 10MR zeolites and have also pores bigger
Química Nova. Publicado em: 2003-12
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10. Caracterização de catalisadores Cu/CeO2/Al2O3 por redução a temperatura programada e atividade para oxidação de CO
The kinetic parameters for the CO oxidation reaction using copper/alumina-modified ceria as catalysts were determined. The catalysts with different concentrations of the metals were prepared using impregnation methods. In addition, the reduction-oxidation behaviour of the catalysts were investigated by temperature-programmed reduction. The activity results s
Química Nova. Publicado em: 2001-02
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11. An aspartate and a water molecule mediate efficient acid-base catalysis in a tailored antibody pocket
Design of catalysts featuring multiple functional groups is a desirable, yet formidable goal. Antibody 13G5, which accelerates the cleavage of unactivated benzisoxazoles, is one of few artificial enzymes that harness an acid and a base to achieve efficient proton transfer. X-ray structures of the Fab-hapten complexes of wild-type 13G5 and active-site variant
National Academy of Sciences.
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12. Design of a “green” one-step catalytic production of ε-caprolactam (precursor of nylon-6)
The ever-increasing industrial demand for nylon-6 (polycaprolactam) necessitates the development of environmentally benign methods of producing its precursor, ε-caprolactam, from cyclohexanone. It is currently manufactured in two popular double-step processes, each of which uses highly aggressive reagents, and each generates substantial quantities of largel
National Academy of Sciences.