Bound Chemical Water
Mostrando 1-12 de 29 artigos, teses e dissertações.
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1. Quantum Chemical Investigation of the Intramolecular Copigmentation Complex of an Acylated Anthocyanin
Anthocyanins are the natural plant pigments responsible for most of the red, blue and purple colors of flowers and fruit. One method of stabilization of the color of anthocyanins in nature is intramolecular copigmentation, in which a copigment molecule covalently attached to one of the sugar residues complexes with the anthocyanin cation chromophore. In the
J. Braz. Chem. Soc.. Publicado em: 2019-03
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2. Evaluation of Portland pozzolan blended cements containing diatomaceous earth
Abstract Clinker replacement by supplementary cementitious materials (SCMs) is one strategy to reduce CO2 emissions of cement industry. Diatomaceous earth, a natural pozzolan, has been used as SCM. So, this study aimed to evaluate two Portland pozzolan blended cements with distinct content of diatomaceous earth (16DE and 49DE) and compare then with a high cl
Cerâmica. Publicado em: 2019-01
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3. CONCRETE MICROESTRUTURE STUDY WITH ADDITION OF UNGROUND RESIDUAL RICE HUSK ASH WITHOUT BURN CONTROL / ESTUDO DA MICROESTRUTURA DO CONCRETO COM ADIÇÃO DE CINZA DE CASCA DE ARROZ RESIDUAL SEM BENEFICIAMENTO
The use of mineral adition in concrete is a widely studied theme for several researchers that looking for features like: save cement for reducing costs, durability improvement to increase mechanical strenght and use of industrial wastes for reducing environmental pollution. This study intend to analize the microstructure of concretes mixtures with ungrounded
Publicado em: 2008
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4. Detecção condutométrica sem contato: uma nova ferramenta para monitoramento de interações biomoleculares em microssistemas analíticos / Contactless conductivity detection: a new tool for monitoring biomolecular interactions on analytical microsystems
The study reported in this thesis shows the application of a capacitively coupled contactless conductivity detection (C4D) for monitoring biomolecular interactions on analytical microsystems. Initially, the analytical performance of the microsystems fabricated in glass, poly(dimethylsiloxane) (PDMS) and polyester-toner (PT) was investigated in order to choos
Publicado em: 2008
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5. Obtenção e caracterização de filmes de TiO2 depositados sobre cerâmica de revestimento via magnetron sputtering DC
Titanium oxide (TiO2) under ultraviolet light becomes catalyst of chemical reactions. This phenomenon can be used to break down hydrocarbon and water molecules bound. Hydrocarbon was changing into water and carbon dioxide. Adsorbed water molecule is degraded by film and form a layer of adsorbed hydroxyl groups (OH), which are able to increase surface energy,
Publicado em: 2007
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6. Avaliação do desenvolvimento de girassol por meio de analise de proteinas e metaloproteinas / Evaluation of sunflower development based on protein metalloprotein analysis
This work describes an evaluation of sunflower (Helianthus annuus L.) growth when it is submitted to seven treatments, and their interrelation with proteins and metalloproteins analyses. Metal ion solutions (Cd, Cu, Pb and Zn) were added to the substrate in four treatments. In another two, used as controls, the plants were irrigated only with deionized water
Publicado em: 2006
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7. A theoretical study oh the effect of "bound" water on the proton chemical shifts of the nucleic acid bases.
Computations are performed on the proton chemical shifts due to hydrogen bonding between the purine and pyrimidine bases of the nucleic acids and water molecules of their first hydration shell. The water molecules should produce measurable shifts essentially for protons of the bases located close to the site of interaction. For the imino protons of the bases
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8. Oxygen exchange in the gamma-phosphoryl group of protein-bound ATP during Mg2+-dependent adenosine triphosphatase activity of myosin.
When ATP binds to myosin in the presence of Mg2+ there follows a rapid cleavage reaction to yield a myosin-product complex whose breakdown is rate-limiting in the overall adenosine triphosphatase reaction at 21 degrees and pH 8.0. Recent kinetic studies on this system have led to the proposal that the cleavage of ATP bound to myosin is reversible. This concl
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9. Effect of total dose infusion of iron dextran on the storage iron content of the human placenta.
In a series of pregnant women with iron deficiency anaemia treated by a total dose infusion of iron dextran, the non-haem iron content of the placenta at term was studied histochemically and by chemical analysis. Within a few days of the infusion the Prussian blue reaction on the placenta was very strong, but was negative by ten days after the infusion. Chem
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10. Freezing and melting water in lamellar structures.
The manner in which ice forms in lamellar suspensions of dielaidoylphosphatidylethanolamine, dielaidoylphosphatidylcholine, and dioleoylphosphatidylcholine in water depends strongly on the water fraction. For weight fractions between 15 and 9%, the freezing and melting temperatures are significantly depressed below 0 degree C. The ice exhibits a continuous m
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11. Evidence for the production of trioxygen species during antibody-catalyzed chemical modification of antigens
Recent work in our laboratory showed that products formed by the antibody-catalyzed water-oxidation pathway can kill bacteria. Dihydrogen peroxide, the end product of this pathway, was found to be necessary, but not sufficient, for the observed efficiency of bacterial killing. The search for further bactericidal agents that might be formed along the pathway
The National Academy of Sciences.
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12. Structural and kinetic studies of lasalocid A (X537A) and its silver, sodium, and barium salts in nonpolar solvents.
The ionophore lasalocid A (X537A) and its metal salts have been investigated by high resolution (270 MHz and 360 MHz) proton nuclear magnetic resonance spectroscopy to obtain structural and kinetic information in nonpolar solution. The proton resonances were assigned from double resonance studies on lasalocid A and on its salts, homologs, isomers, and chemic