Calibration Model
Mostrando 1-12 de 295 artigos, teses e dissertações.
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1. Simultaneous Quantification of Amorphous and Crystalline Valsartan in Tablets Using Raman Spectroscopy and Chemometrics Tools
Valsartan is an antihypertensive active pharmaceutical ingredient (API), it is used in the amorphous state in the commercial products. As amorphous materials are metastable, amorphous valsartan can crystallize to valsartan E, promoting changes in the dissolution and bioavailability of the drug. Tablets containing metastable forms of APIs need special conditi
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Quantification of Carbon Dioxide (CO2), Methane (CH4), and Nitrous Oxide (N2O) Using Near Infrared Spectroscopy and Multivariate Calibration in High Humidity Levels
In this work we developed a promising analytical method combining Fourier transform near-infrared (FT-NIR) spectroscopic technique and first-order multivariate calibration using partial least-squares (PLS) model to simultaneously quantify the main greenhouse gases (GHG’s): methane (CH4), carbon dioxide (CO2), nitrous oxide (N2O) and water vapor (H2O). The
Journal of the Brazilian Chemical Society. Publicado em: 2022
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3. Nomogram for predicting post-traumatic hydrocephalus after decompressive craniectomy for traumatic brain injury
SUMMARY OBJECTIVE: This study aimed to develop and validate a practical nomogram to predict the occurrence of post-traumatic hydrocephalus in patients who have undergone decompressive craniectomy for traumatic brain injury. METHODS: A total of 516 cases were enrolled and divided into the training (n=364) and validation (n=152) cohorts. Optimal predictors w
Revista da Associação Médica Brasileira. Publicado em: 2022
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4. QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O
This work reports a multivariate calibration partial least square regression (PLS) model to quantify the liquid-phase concentrations of 2-amino-2-methyl-1-propanol (AMP), piperazine (PZ), bicarbonate, PZ monocarbamate, and PZ dicarbamate during the absorption/desorption process by Fourier Transform Mid-Infrared spectroscopy (mid-FTIR). The model could predic
Química Nova. Publicado em: 2022
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5. Risk-Prediction Model for Transfusion of Erythrocyte Concentrate During Extracorporeal Circulation in Coronary Surgery
Abstract Introduction: Our objective was to identify preoperative risk factors and to develop and validate a risk-prediction model for the need for blood (erythrocyte concentrate [EC]) transfusion during extracorporeal circulation (ECC) in patients undergoing coronary artery bypass grafting (CABG). Methods: This is a retrospective observational study inclu
Braz. J. Cardiovasc. Surg.. Publicado em: 2021-06
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6. Determination of carrageenan in jellies with new methylene blue dye using spectrophotometry, smartphone-based colorimetry and spectrophotometric titration
Abstract Carrageenan is a seaweed polysaccharide widely used as a food gelling and thickening agent. The New Methylene Blue dye was tested as an analytical reagent for the quantification of carrageenan in commercial jelly samples. The main spectral peaks of the dye decrease with increasing carrageenan-to-dye molar ratio up to 1. Three analytical procedures w
Food Sci. Technol. Publicado em: 2021-06
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7. Survival nomogram for patients with bone metastatic renal cell carcinoma: A population-based study
ABSTRACT Purpose: Increased attention has been focused on the survival of renal cell carcinoma (RCC) patients with bone metastasis. This study proposed to establish and evaluate a nomogram for predicting the overall survival (OS) and cancer-specific survival (CSS) of RCC patients with bone metastasis. Materials and Methods: RCC patients with bone metastasi
Int. braz j urol.. Publicado em: 2021-03
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8. FITTING AND CALIBRATING A MIXED-EFFECTS SEGMENTED TAPER MODEL FOR BRUTIAN PINE
ABSTRACT Taper models are one of several necessary tools in modern forest inventory, giving information on diameter at any point along the tree stem and this information can also be used to estimate stem volume. In this study, we used nonlinear mixed-effects (NLME) modeling approach to minimize existing statistical problems in constructing taper equations. A
CERNE. Publicado em: 2020-12
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9. APPLICABILITY OF THE SWAT HYDROLOGICAL MODEL IN THE MUCURI RIVER BASIN
ABSTRACT Land-use changes promote significant variations in streamflow regimes, and hydrological models allow studying their impacts. Based on this approach, this study aimed to assess the applicability of the SWAT model for different land-use scenarios and their respective impacts on the flow regime of the Mucuri River. The average monthly and daily water b
Eng. Agríc.. Publicado em: 2020-10
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10. Omega-3 and Omega-6 Determination in Nile Tilapia’s Fillet Based on MicroNIR Spectroscopy and Multivariate Calibration
Tilapia (Oreochromis niloticus) is the most cultivated fish species in Brazil. Studies have shown that fish consumption is related to the prevention of cardiovascular diseases due to its high contents of polyunsaturated fatty acids, as omega-3 (n-3) and omega-6 (n-6). In this sense, a new method to determine omega-3 and omega-6 by near-infrared (NIR) spectro
J. Braz. Chem. Soc.. Publicado em: 2020-09
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11. REGRESSÃO MULTIVARIADA POR OPLS E PLS DOS ESPECTROS DE RMN DE 1H DE MISTURAS DIESEL/BIODIESEL DE MAFURRA PARA ESTIMATIVA DO TEOR DE BIODIESEL
Two methodologies were developed to monitor the biodiesel content of mafurra in mixtures with diesel using hydrogen nuclear magnetic resonance (1H NMR) Spectroscopy combined with the multivariate regression by orthogonal projections to latent structure (OPLS) and partial least squares (PLS). The efficiency of these methodologies was analyzed based on the fig
Quím. Nova. Publicado em: 20/07/2020
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12. Double or triple-expressor lymphomas: prognostic impact of immunohistochemistry in patients with diffuse large B-cell lymphoma
Mid-Infrared absorption spectroscopy associate with the Partial Least Squares regression is the official method to monitor Brazilian commercial diesel quality. This method, however, uses solvents and a large number of samples for the construction of the calibration curves, which generates waste and increases the time needed for the analysis. In order to deve
Hematol., Transfus. Cell Ther.. Publicado em: 2020-06