Carboxylic Acids Reduction
Mostrando 1-12 de 23 artigos, teses e dissertações.
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1. Upgrade of Biofuels Obtained from Waste Fish Oil Pyrolysis by Reactive Distillation
Bio-oil is classified as second-generation biofuel and it is produced mainly through the pyrolysis of a waste lignocellulosic biomass base. The application of this product is still very limited, due to some of its chemical characteristics. This paper presents a proposal for the reduction of the acidity of bio-oil obtained from waste fish oil, previously prod
J. Braz. Chem. Soc.. Publicado em: 2015-02
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2. Endophytic fungi producing of esterases: evaluation in vitro of the enzymatic activity using pH indicator
A sensitive and efficient colorimetric method was optimized for detection of esterase enzymes produced by endophytic fungi for development of High-Throughput Screening (HTS). The fungi were isolated and obtained previously from plant species of Cerrado and Atlantic Forest located in areas of environmental preservation in the State of Sao Paulo / Brazil, as p
Braz. J. Microbiol.. Publicado em: 10/01/2014
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3. Estudo qualitativo e quantitativo de biomarcadores ácidos e hidrocarbonetos presentes em óleos da Bacia Potiguar / Qualitative and quantitative study of acidic and hydrocarbon biomarkers of oil from the Potiguar Basin
rabalho foram sintetizados quatro biomarcadores ácidos, a saber: ácido 5b (H) colânico (2), 5a (H) homopregnânico (4), 8,13-tetraidrocopálico (6) e 15-isocopálico (7). Para tanto, foram utilizadas matérias primas comerciais (ácido litocólico e estigmasterol) e o ácido copálico (extraído e purificado a partir de bálsamo de copaíba). Também foi
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 07/12/2011
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4. Otimização do processo de mineralização de compostos orgânicos utilizando sistemas eletro-Fenton e fotoeletro Fenton por irradiação UV artificial e solar
OPTIMIZATION OF THE MINERALIZATION PROCESS OF ORGANIC COMPOUNDS USING ELECTRO-FENTON AND PHOTO-FENTON SYSTEMS BY ARTIFICIAL AND SOLAR UV IRRADIATION Electrochemical advanced oxidation processes based on the Fentons reaction, such as electro-Fenton (EF) and photoelectro-Fenton (PEF) using artificial and solar UV irradiation were employed in the treatment of e
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 30/09/2011
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5. Influência da adição de hardfats sobre as propriedades tecnológicas do óleo de palma visando a aplicação em chocolates / Influence of the addition of hardfats on technological properties of palm oil aiming the application in chocolate
Palm threes (Elaesis guineensis) are one of the main sources of industrial vegetable oils. Palm oil, extracted from the pulp of the fruit is widely used in the food industry, as for instance, in the production of chocolates. However, in many applications the amount of palm oil added is restricted by its preferential ß - polymorphism, slow crystallization ra
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 30/09/2011
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6. Estudo teorico do mecanismo da reação de redução do acido carboxilico utilizando o borohidreto de sodio e um eletrofilo / Theoretical study of the carboxylic acid reduction reaction mechanism using sodium borohydride and on electrophile
The main objective of this work was to analyze four theoretical mechanisms to the reduction (in gas-phase) of acetic acid to ethanol. It was employed NaBH4 in presence of an electrophile (H2SO4). All the calculations were carried out at CBSQB3 method using the Gaussian 98 program. It was found that this methodology suceeds in predicting proton and electron a
Publicado em: 2008
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7. Matéria orgânica de Latossolos Húmicos: análises térmica e espectroscópica, efeito do uso e correção química / Organic matter of humic Latosol (Oxisol): thermal and spectroscopic analyses, land use and chemical correction
The objective of this study was to contribute to the clarification of several aspects related to the behavior of organic matter (OM) in highly weathered tropical soils. Six samples of humic A horizon Latosol were collected from three sites in Minas Gerais: i) Sericita, (under coffee crop, pasture, ferns and Atlantic Forest fragment); ii) Mutum (under Atlanti
Publicado em: 2008
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8. Characterization of commercial ceramic adsorbents and its application on naphthenic acids removal of petroleum distillates
The mixture of carboxylic acids present in petroleum oil and directly responsible for its acidity and corrosiveness in liquid phase during the refine process is denominated "naphthenic acids". These acids are also present in distilled fraction of petroleum, causing several problems in final products quality. A possible way to remove the carboxilic acids from
Materials Research. Publicado em: 2007-06
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9. Redução eletroquímica de cinamatos de metila orto-substituídos / Electrochemical reduction of ortho-substituted methyl cinnamates
The synthesis and electrochemical reduction in DMF of some ring substituted cinnamic esters are described. The main objective if this work is to verify the influence of the substituents on the electrohydrodimerization (EHD). The substrates studied were the methyl esters of o-methyl- (1), o-chloro- (2), o-nitro- (3), m,p-dichloro- (4), m-chloro- (5), p-chloro
Publicado em: 2004
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10. Redução de amidas por boranos
Despite the fact that boranes are frequently used in amide reductions, the reaction mechanisms of the involved are note well known. This work presents the results of a bibliographic search on probable amide reduction mechanisms and an analysis of the existing literature. Steric and electronic effects were considered in light of reactivity since it could be c
Química Nova. Publicado em: 2002-05
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11. Liquefação direta do bagaço de cana com formiato de sodio em meio aquoso
The direct liquefaction of sugar cane bagasse was studied in water with formate/argon(A) and, for comparative purposes, with Ca(OH)2/CO(B) and Ca(OH)2/argon(C). Conversion of sugar cane bagasse and yield for extracted oil in the three systems increase with temperature and are higher with reaction systems A and B. The experiments show that the direct applicat
Publicado em: 1984
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12. Transformations of Halogenated Aromatic Aldehydes by Metabolically Stable Anaerobic Enrichment Cultures
Metabolically stable enrichment cultures of anaerobic bacteria obtained by elective enrichment of sediment samples from the Baltic Sea and Gulf of Bothnia have been used to study the oxidation and reduction of the aldehyde group of various halogenated aromatic aldehydes. During the transformation of 5- and 6-chlorovanillin, 6-bromovanillin, 3-chloro-4-hydrox