Artigos científicos, teses e dissertações
Publicados nas melhores instituições de ensino

Imagem pública e divulgação da química: desafios e oportunidades

Chemical knowledge plays a central role in the economical and social development of a nation. Chemistry is considered a key science, which provides the means and meanings that fuel the advancement of other fields of knowledge. However, the public image of chemistry is often assoc...

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Space- and time-resolved spectrophotometry in microsystems

This work describes a simple optical method for obtaining, in a single still-capture image, the continuous absorbance spectra of samples at multiple locations of microsystems. This technique uses an unmodified bright-field microscope, an array of microlenses, and a diffraction gr...

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Construction of a supercritical fluid extraction (SFE) equipment: validation using annatto and fennel and extract analysis by thin layer chromatography coupled to image

Abstract The present work describes setting up a laboratory unit for supercritical fluid extraction. In addition to its construction, a survey of cost was done to compare the cost of the homemade unit with that of commercial units. The equipment was validated using an extraction ...

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NMR chemical shift imaging in three dimensions.

A method for obtaining the three-dimensional distribution of chemical shifts in a spatially inhomogeneous sample using Fourier transform NMR is presented. The method uses a sequence of pulsed field gradients to measure the Fourier transform of the desired distribution on a rectan...

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Fluorescence lifetime imaging of free and protein-bound NADH.

We introduce a methodology, fluorescence lifetime imaging (FLIM), in which the contrast depends on the fluorescence lifetime at each point in a two-dimensional image and not on the local concentration and/or intensity of the fluorophore. We used FLIM to create lifetime images of ...

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Response of microbial adhesives and biofilm matrix polymers to chemical treatments as determined by interference reflection microscopy and light section microscopy.

The polymers involved in the adhesion of Pseudomonas fluorescens H2S to solid surfaces were investigated to determine whether differences between cell surface adhesives and biofilm matrix polymers could be detected. Two optical techniques, i.e., interference reflection microscopy...

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Rapid Method for Analyzing Bacterial Behavioral Responses to Chemical Stimuli

A rapid method was developed to analyze bacterial behavioral responses to chemical stimuli. Digital image processing was used to detect the accumulation of bacteria at the mouth of a capillary containing an attractant. The accumulation of bacteria was determined from the total nu...

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MICROSCOPIA DE FORÇA ATÔMICA IN SITU E MICRODUREZA DE DENTINA SUBMETIDA A SUBSTÂNCIAS QUELANTES / IN SITU ATOMIC FORCE MICROSCOPY AND MICROHARDENESS OF DENTIN THROUGHOUT THE CHELATION PROCESS

Instrumentation methods currently used in endodontic therapy create a residual layer composed of organic and inorganic material that frequently retains bacteria and their subproducts. The available methods to remove this smear layer include chemical etching, ultrasonic and laser ...

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Preparation of nanodimensional CdS by chemical dipping technique and their characterization

A simple and cost effective chemical technique has been utilized to grow cadmium sulphide (CdS) nanoparticles at room temperature. The sample is characterized with XRD (X-ray diffractometer), SEM (Scanning electron microscope), TEM (Transmission electron microscope) and UV-VIS sp...

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RAPID DETECTION OF VITAMIN C CONTENT IN FRUITS AND VEGETABLES USING A DIGITAL CAMERA AND COLOR REACTION

In this study, we propose a novel method to determine the vitamin C content in fruits and vegetables. The proposed method exploits the image and data processing abilities of computers by coupling a digital camera and a color reaction. An image acquisition device was developed to ...

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Sensores eletroquímicos: considerações sobre mecanismos de funcionamento e aplicações no monitoramento de espécies químicas em ambientes microscópicos

Electrochemical sensors have attracted considerable attention in recent years because they provide data about the chemical state of our surroundings and the dynamics of the chemical transformations in the form a spatially resolved image. Particular interest has been directed to m...

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Two-dimensional crystals of cholera toxin B-subunit-receptor complexes: projected structure at 17-A resolution.

The B subunit of cholera toxin forms two-dimensional crystals when bound to its membrane receptor, ganglioside GM1, in phospholipid layers. A rectangular crystal lattice gives diffraction extending to 15-A resolution in negative stain, and image-processing of electron micrographs...

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MONOENERGETIC AND POLYENERGETIC GAMMA RAY COMPUTER TOMOGRAPHY FOR MULTIPHASE SYSTEMS ANALYSIS / Análise de sistemas multifásicos utilizando tomografia computadorizada Gama monoenergética e polienergética

It is important to recognize that at the heart of chemical transformations in all process and energy industries is multiphase reator technology, as over 99% of reator systems require the presence of more than one phase for proper operation. Tomography is a powerful technique capa...

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31P saturation transfer and phosphocreatine imaging in the monkey brain.

31P magnetic resonance imaging with chemical-shift discrimination by selective excitation has been employed to determine the phosphocreatine (PCr) distribution in the brains of three juvenile macaque monkeys. PCr images were also obtained while saturating the resonance of the gam...

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Química verde, os desafios da química do novo milênio

The fundamental concepts of the green chemistry are highlighted in order to present the enormous number of challenges to develop a new chemistry in research, industry and education. The practice of an environmental friendly chemistry are presented to improve the economics of chem...

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A DNA Spiegelmer to staphylococcal enterotoxin B

Bacterial staphylococcal enterotoxin B is involved in several severe disease patterns and it was therefore used as a target for the generation of biologically stable mirror-image oligonucleotide ligands, so called Spiegelmers. The toxin is a 28 kDa protein consisting of 239 amino...

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Spectrum and chemical composition of the remarkable planetary nebula NGC 6537

Observations with the image tube scanner at the Shane 3-m telescope are combined with data obtained with the International Ultraviolet Explorer to assess the spectrum of the remarkable high-excitation planetary nebula NGC 6537. We have analyzed the spectrum of this nitrogen-rich ...

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Ultraviolet spectrum and probable chemical composition of the high-excitation planetary nebula M1-1

One of the highest excitation planetary nebulae known, M1-1, was studied with the image-tube scanner on the Shane 3-m telescope at Lick Observatory and with the International Ultraviolet Explorer. Large fractions of abundant elements such as C, N, O, S, and Ar exist in unobservab...

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Mini-channel Two Phase Flow of Hydrogen Peroxide: Decomposition with Silver Catalyst

ABSTRACT Hydrogen peroxide is a chemical compound which is commonly used as a disinfectant at lower concentrations. The chemical is called as a green propellant for space applications. Water and oxygen are the products after self-decomposition of the compound at higher concentrat...

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