Cross Coupling
Mostrando 1-12 de 171 artigos, teses e dissertações.
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1. Finite element computational development for thermo-mechanical analysis of plane steel structures exposed to fire
Abstract This article presents a numerical formulation based on finite element procedures for application in nonlinear thermo-mechanical analyses of steel planar structures under fire condition. The mechanical properties of structural elements degrade when subjected to high temperatures, resulting in significant reductions in strength and stiffness. Under th
REM - International Engineering Journal. Publicado em: 2022
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2. People with amputation and musculoskeletal pain show reduced electrical activity of Alpha brain waves: cross-sectional study
RESUMO JUSTIFICATIVA E OBJETIVOS: A amputação acarreta quadros clínicos associados, como a dor musculoesquelética (DME), que causa sofrimento e interfere na vida do paciente. Por isso, o desenvolvimento de métodos diagnósticos para mensurar essas alterações são incentivados, como a eletroencefalografia quantitativa (EEGq). O objetivo deste estudo f
BrJP. Publicado em: 2022
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3. SYNERGISMS BETWEEN METAL AND PHOTOREDOX CATALYSIS: DECONVOLUTING COMPLEX SYSTEMS
This review briefly describes the evolution of organometallic chemistry and photoredox catalysis as independent fields; followed by a more in-depth presentation and discussion of representative examples derived from their synergistic combination, which generally leads to powerful cross-coupling protocols. In this context, the rational deconvolution of these
Quím. Nova. Publicado em: 20/07/2020
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4. Palladium Nanoparticles Supported on β-cyclodextrin Functionalised Poly(amido amine)s and their Application in Suzuki-Miyaura Cross-Coupling Reactions
Herein, the synthesis, characterization and catalytic application of an organic-inorganic, palladium (Pd)-containing hybrid material, poly(amidoamine)-cyclodextrin (Pd@PAAs-CD), is reported as an efficient catalyst for Suzuki-Miyaura coupling reactions. The structure of Pd@PAAs-CD was confirmed by Fourier transform infrared spectroscopy (FTIR), transmission
J. Braz. Chem. Soc.. Publicado em: 12/08/2019
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5. Modelos de desenvolvimento da inovação em pequenas e médias empresas do setor aeronáutico no Brasil e no Canadá
Resumo O presente trabalho apresenta os resultados de uma pesquisa cujo objetivo foi gerar conhecimentos mais detalhados sobre como ocorre o processo de desenvolvimento da inovação em pequenas e médias empresas (PME) do setor aeronáutico. Utilizam-se como base conceitual cinco modelos de inovação tecnológica oferecidos pela literatura: linear, linear
Gest. Prod.. Publicado em: 28/03/2019
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6. Development and characterization of an immunoaffinity column for the detection of danofloxacin residues in milk samples
Abstract In this study, an immunoaffinity column was prepared by covalently coupling of polyclonal antibody against danofloxacin (DAN) with chitosan microparticles and its potential application to selective extraction of DAN from food samples was also evaluated. The produced antibody exhibited high sensitivity, with an IC50 value of 4.56 ng/mL towards DAN,
Food Sci. Technol. Publicado em: 30/07/2018
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7. In vivo chemotherapeutic insight of a novel isocoumarin (3-hexyl-5,7-dimethoxy-isochromen-1-one): Genotoxicity, cell death induction, leukometry and phagocytic evaluation
Abstract Chemotherapy is one of the major approaches for the treatment of cancer. Therefore, the development of new chemotherapy drugs is an important aspect of medicinal chemistry. Chemotherapeutic agents include isocoumarins, which are privileged structures with potential antitumoral activity. Herein, a new 3-substituted isocoumarin was synthesized from 2-
Genet. Mol. Biol.. Publicado em: 2017-09
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8. Suzuki-Miyaura Coupling between 3-Iodolawsone and Arylboronic Acids. Synthesis of Lapachol Analogues with Antineoplastic and Antileishmanial Activities
A series of 2-hydroxy-3-arylnaphthalene-1,4-diones (3-aryllawsones) were synthesized by Suzuki-Miyaura cross coupling reaction of 3-iodolawsone with arylboronic acids/esters. The hydroxylated resulting products were transformed into their corresponding N,N-diethyl carbamates. The antineoplastic and antileishmanial activities of the compounds were evaluated a
J. Braz. Chem. Soc.. Publicado em: 2017-08
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9. Reduced Order Modeling of Composite Laminates Through Solid-Shell Coupling
ABSTRACT: Composite laminates display a complex mechanical behavior due to their microstructure, with a through-thickness variation of the displacement and stress fields that depends on the fiber orientation in each layer. Aiming to develop reduced-order numerical models mimicking the real response of composite structures, we investigated the capability and
J. Aerosp. Technol. Manag.. Publicado em: 26/06/2017
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10. Numerical Material Model for Composite Laminates in High-Velocity Impact Simulation
Abstract A numerical material model for composite laminate, was developed and integrated into the nonlinear dynamic explicit finite element programs as a material user subroutine. This model coupling nonlinear state of equation (EOS), was a macro-mechanics model, which was used to simulate the major mechanical behaviors of composite laminate under high-veloc
Lat. Am. j. solids struct.. Publicado em: 2017
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11. SÍNTESES TOTAIS NO BRASIL EMPREGANDO ACOPLAMENTOS CRUZADOS MEDIADOS POR PALÁDIO
This article aims to show the selected total syntheses of organic compounds conducted by Brazilian researchers, performed in Brazil, which have employed a palladium catalyzed cross-coupling reaction as key step. We intended to thus create an account, although restricted to the use of palladium, showing the evolution and current state of art of Synthetic Orga
Quím. Nova. Publicado em: 2016-08
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12. PdCl2 Immobilized in Polyacrylamide: a Low Cost and Eco-Friendly Catalyst for Suzuki-Miyaura Reactions
PdCl2 immobilized in polyacrylamide (PAM), named Pd/PAM, produced at an extremely low cost, was found to be an efficient catalyst for Suzuki-Miyaura cross-coupling reactions. Iodo- and bromoarenes may couple with phenylboronic acid under eco-friendly conditions (i.e., phosphine-free and with ethanol as the solvent) to give excellent product yields. Aryl chlo
J. Braz. Chem. Soc.. Publicado em: 2016-04