Cyclic Formation
Mostrando 1-12 de 525 artigos, teses e dissertações.
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1. Voltammetric Generation and Kinetic Stability of Nitro Anion Radical from Nitrofurazone in Ionic Liquids
The nitrofurazone (NF) electrochemical reduction has been studied by cyclic voltammetry (CV) and square wave voltammetry (SWV) in non-aqueous medium using three different ionic liquids (IL): BMImTf2N, BMImBF4 and BMMImTf2N, having a carbon fiber microelectrode as working electrode. In all of them, two reversible cathodic peaks were recorded for NF. Under hig
J. Braz. Chem. Soc.. Publicado em: 2021-04
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2. DNA Damage by Endogenous and Exogenous Aldehydes
The present overview describes the formation of deoxyribonucleic acid (DNA) adducts from endogenous and exogenous aldehydes, such as acetaldehyde, acrolein, crotonaldehyde, malonaldehyde, 4-hydroxy-2-nonenal and 2,4-decadienal. Malonaldehyde reacts with 2’-deoxyguanosine, 2’-deoxyadenosine, and 2’-deoxycytidine, yielding cyclic pyrimidopurinone and acy
J. Braz. Chem. Soc.. Publicado em: 21/10/2019
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3. Corrosion Behavior of Austenitic Stainless Steels in CO2-Saturated Synthetic Oil Field Formation Water
The corrosion behavior of austenitic and superaustenitic stainless steels was investigated in carbon dioxide-saturated synthetic oil field formation water using cyclic polarization tests. In order to measure the effect of carbon dioxide pressure, the samples were also exposed in a pressurized medium containing carbon dioxide and synthetic air. For this purpo
Mat. Res.. Publicado em: 05/09/2019
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4. Effect of Warm Rolling on the Corrosion and Mechanical Properties of UNS S32205 Duplex Stainless Steel
Duplex stainless steel (DSS) has been considered as an excellent alternative for applications where high corrosion resistance and high mechanical strength are required. Therefore, microstructure and properties of DSS remain topics of much interest. For this purpose, the effect of warm-rolling was studied in a duplex stainless steel. The focus of this work wa
Mat. Res.. Publicado em: 02/09/2019
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5. BDD-Electrolysis of Oxalic Acid in Diluted Acidic Solutions
Boron doped diamond films (BDD) are the most studied electrocatalytic materials and their efficiency for removing organic compounds is attributed to their ability to produce a large amount of hydroxyl radicals by the electrolysis of water. However, some organic compounds are easy to degrade than others, as well as they also interact with BDD surface. Thus, i
J. Braz. Chem. Soc.. Publicado em: 04/07/2019
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6. MOLECULE DESIGN AND PROPERTIES OF CYCLIC ENERGETIC MATERIALS BASED ON NITROGUANIDINE AND 1,1-DIAMINO-2,2-DINITROETHENE
A series of cyclic energetic derivatives based on nitroguanidine and 1,1-diamino-2,2-dinitroethene were theoretically designed. The spatial structures, infrared spectrometry, heats of formation, electronic structures, detonation properties, and thermal stabilities of these designed compounds were fully investigated by density functional theory. It is found t
Quím. Nova. Publicado em: 2019-02
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7. Determinación del área de superficie real de electrodos de titanio modificado con platino por voltamperometría cíclica
ABSTRACT The surface area of Ti/TiO2-Pt electrodes (ASr) in contact with 0.010 M HClO4 solutions was determined by Cyclic Voltammetry (CV) and Atomic Force Microscopy (AFM) techniques. The Ti/Pt/TiO2 electrodes with different amounts of electrodeposited Pt (1, 5 and 10 seconds) were polarized up to 1.5 V vs. Ag/AgCl (sat. KCl) and stabilized at the final pot
Matéria (Rio J.). Publicado em: 19/07/2018
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8. Efecto electrocatalítico de nanopartículas bimetálicas de Ag y Cd hacia la reducción de iones nitrato y/o nitrito
ABSTRACT The electrocatalytic effect of Cd-Ag bimetallic nanoparticles supported on highly oriented pyrolytic graphite (HOPG) and vitreous carbon (VC) substrates was evaluated for the nitrate and/or nitrite ions reduction reaction. For this, in a first stage, the metallic and bimetallic deposits were obtained on the carbonaceous substrates (CS) using the ele
Matéria (Rio J.). Publicado em: 19/07/2018
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9. Pseudocapacitance Properties of Co3O4 Nanoparticles Synthesized Using a Modified Sol-Gel Method
This work reports the synthesization of nanoparticles cobalt oxide (Co3O4) with no secondary phase by a modified sol-gel method and its structural morphological and electrochemical characterizations. FTIR, XRD and Raman analysis showed the formation of spinel cobalt oxide with no secondary phase. TEM images revealed that an undefined morphology with average
Mat. Res.. Publicado em: 05/02/2018
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10. Identification of Anti-Inflammatory and Anti-Hypertensive Drugs as Inhibitors of Bacterial Diguanylate Cyclases
Biofilms are widely present in many human chronic infections, often more resistant to treatment with antibiotics. Bacterial diguanylate cyclases (DGCs) synthesize cyclic dimeric guanosine monophosphate (c-di-GMP) from two guanosine-5'-triphosphate (GTP) molecules. c-di-GMP is a central second messenger controlling biofilm formation, turning this class of enz
J. Braz. Chem. Soc.. Publicado em: 2018-02
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11. Influence of heat treatments on the microstructure and degree of sensitization of base metal and weld of AISI 430 stainless steel
ABSTRACT AISI 430 is a non-stabilized ferritic stainless steel grade with carbon content lower than 0.12%.After hot and cold rolling this material is annealed. The slow cooling after soaking at temperatures between 900oC and 1000oC promotes the formation of a high quantity of carbides and nitrides, while the rapid cooling partially suppresses the formation o
Matéria (Rio J.). Publicado em: 08/01/2018
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12. Kinetics Oxidation and Characterization of Cyclically Oxidized Layers at High Temperatures for FeMnSiCrNiCe and FeSiCrNi Alloys
Conventional stainless steels are used in cyclic oxidation, but the high amount of Cr and mainly Ni increase the price of these alloys. The objective of the present study was to assess the cyclic oxidation resistance of FeSiCrNi and FeMnSiCrNiCe alloys in comparison to AISI 304 and AISI 310 stainless steels by evaluating the oxidation kinetics and using char
Mat. Res.. Publicado em: 18/09/2017