Electroanalysis
Mostrando 1-12 de 13 artigos, teses e dissertações.
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1. An overview of the Brazilian contributions to Green Analytical Chemistry
Abstract: Green Analytical Chemistry (GAC) is a research field that seeks for more sustainable analytical approaches to minimize the toxicity and amounts of wastes without hindering the analytical performance. This is a trend in Analytical Chemistry worldwide and because of the diversity of innovations on this subject, Brazil stands out as the third in the l
An. Acad. Bras. Ciênc.. Publicado em: 18/04/2019
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2. Antioxidant activity evaluation of dried herbal extracts: an electroanalytical approach
ABSTRACT The prevention of chronic and degenerative diseases, is a health concern deeply associated with oxidative stress. Such progressive phenomena can be avoided through exogenous antioxidant intake, which set up a reductant cascade, mopping up damaging free radicals. Medicinal herbs are commonly associated with high antioxidant potential, and hence their
Rev. bras. farmacogn.. Publicado em: 2018-06
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3. Improved NADH Electroanalysis on Nickel(II) Phthalocyanine Tetrasulfonic Acid/Calf Thymus Deoxyribonucleic Acid/Reduced Graphene Oxide Composite
This work describes the electrochemical performance of a novel composite based on nickel tetrasulfonated phthalocyanine (NiTsPc), deoxyribonucleic acid from calf thymus (CT-DNA) and reduced graphene oxide (rGO) for the electroanalysis of reduced β-nicotinamide adenine dinucleotide (NADH), through electrocatalytic oxidation. The modified electrode was denote
J. Braz. Chem. Soc.. Publicado em: 2017-09
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4. Synthesis of Poly(Vinylferrocene) Perchlorate/Poly(3,3’-Diaminobenzidine) Modified Electrode in Dichloromethane for Electroanalysis of Hydroquinone
Poly(vinylferrocenium) perchlorate-poly(3,3’-diaminobenzidine) (PVF+ClO4–-PDAB) composite film was synthesized electrochemically for the first time on Pt disc electrode in a dichloromethane solution containing poly(vinylferrocene) (PVF) polymer, 3,3’-diaminobenzidine (DAB) monomer and tetrabutylammonium perchlorate as supporting electrolyte. This modif
J. Braz. Chem. Soc.. Publicado em: 2015-09
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5. Construção de eletrodo de grafite retirado de pilha comum: aplicações didáticas
This paper presents a proposal for using recycled graphite electrodes obtained from exhausted commercial 1.5 V batteries and its application in electroanalysis. The electrode could be prepared by the students and applied in the simple didactic experiments suggested, such as determination of active electrode area, cyclic voltammetry and useful potential range
Quím. Nova. Publicado em: 2014-07
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6. Flavonoid electrochemistry: a review on the electroanalytical applications
Flavonoids are polyphenolic compounds widespread in vegetal kingdom. They present a C-15 skeleton, which is divided into three units A, B and C. Unit C is an oxygen containing heterocyclic, whose oxidation state and saturation level define major subclasses. Units A and B are aromatic rings, in which four major types of substituents, i. e. hydroxyl, methoxyl,
Rev. bras. farmacogn.. Publicado em: 10/05/2013
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7. Eletrodos modificados com monocamadas auto-organizadas de alcanotióis: uma abordagem sobre a transferência eletrônica / Electrode surface modified with alkanothiols self-assembled monolayers: an electron transfer approach
The modification of electrode surfaces with self-assembled monolayer (SAM) is one of the top subjects in electrochemistry and electroanalysis, mainly due to its much enhanced biocompatibility. In this study, the focuses are centered in the electron transfer through SAMs of alkanothiols assembled onto gold electrode surfaces. In order to investigate the elect
Publicado em: 2008
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8. Conductive diamond electrodes for water purification
Nowadays, synthetic diamond has been studied for its application in wastewater treatment, electroanalysis, organic synthesis and sensor areas; however, its use in the water disinfection/purification is its most relevant application. The new electrochemistry applications of diamond electrodes open new perspectives for an easy, effective, and chemical free wat
Materials Research. Publicado em: 2007-12
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9. Chemometric methods in the electrochemical studies of phenols on boron-doped diamond films / Metodos quimiometricos em estudos eletroquimicos de fenois sobre filmes de diamante dopado com boro
The subject of this work is the application of chemometric methods in the analysis of the data obtained from electrochemical measurements of phenol compounds on boron-doped diamond electrodes (BDD). BDD films were grown from ethanol and characterized using different techniques. These materials showed good electrochemical qualities. A comparison between BDD a
Publicado em: 2007
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10. Development of electroanalytical methods (Stripping Analysis and Capillary Electrophoresis) for the determination of metals and anions in fuels and petroleum-based products / Desenvolvimento de métodos eletroanalíticos (análise por redissolução e eletroforese capilar) para a determinação de metais e ânions em combustíveis e derivados de petróleo
Neste trabalho foram desenvolvidos métodos eletroanalíticos (redissolução potenciométrica e voltamétrica) para a determinação de metais (mercúrio, cobre, chumbo e zinco) em petróleo, óleo diesel, óleo lubrificante e álcool combustível. Para analisar álcool, foi também desenvolvido um método por eletroforese capilar, que possibilita a determi
Publicado em: 2006
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11. Development and characterization of modified electrodes with conducting polymer materials for electroanalytical detection of pesticides. / Desenvolvimento e caracterização de materiais de eletrodos modificados com polímeros condutores para a determinação eletroanalítica de pesticidas.
O estudo de polímeros condutores desperta um enorme interesse científico e tecnológico devido às diversas aplicações possíveis para esses materiais, como o desenvolvimento de dispositivos eletro-eletrônicos e sensores. Através de processos de dopagem esses polímeros tornam-se eletroativos, possibilitando por meio de técnicas eletroquímicas a dete
Publicado em: 2005
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12. O uso de radiação ultravioleta para o pré-tratamento de amostras em análise inorgânica
The basic principles of UV irradiation as sample pre-treatment step and its potential for inorganic analysis are illustrated and discussed through significant examples from the literature. Not only does this overview cover the classical applications of this technique in the decomposition of organic matter in electroanalysis, but it also presents recent trend
Química Nova. Publicado em: 2003-12