Electrochemical Cells
Mostrando 1-12 de 254 artigos, teses e dissertações.
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1. Electrochemical Preparation and Evaluation of Cytotoxic Activity of Methoxyl-oxo-biseugenol, a New Oxidized Derivative of Biseugenol
Electrochemical procedures have emerged as a powerful tool for the synthesis of complex organic molecules including transformation of natural products. In this study, the electrosynthesis of biseugenol in MeOH afforded one new oxidized derivative, which was characterized as methoxyl-oxo-biseugenol (MOB) by nuclear magnetic resonance (NMR) and electrospray io
J. Braz. Chem. Soc.. Publicado em: 2021-05
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2. Nickel-Cerium Layered Double Hydroxide as Electrocatalyst for Glycerol Oxidation
A new nickel based layered double hydroxide nanomaterial, Ni0.8Ce0.2-LDH, constituted by about 3 nm large nanoparticles exhibiting enhanced electrocatalytic properties towards oxidation of glycerol in alkaline media, was prepared by incorporation of 20 wt.% of CeIII ions into α-nickel hydroxide. This can be oxidized to CeIV, as demonstrated by X-ray photoel
J. Braz. Chem. Soc.. Publicado em: 2020-11
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3. COVID-19 and stroke: a thromboembolic hypothesis
A new nickel based layered double hydroxide nanomaterial, Ni0.8Ce0.2-LDH, constituted by about 3 nm large nanoparticles exhibiting enhanced electrocatalytic properties towards oxidation of glycerol in alkaline media, was prepared by incorporation of 20 wt.% of CeIII ions into α-nickel hydroxide. This can be oxidized to CeIV, as demonstrated by X-ray photoel
Rev. Assoc. Med. Bras.. Publicado em: 2020-11
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4. Supramolecular Approach in Energy Conversion Devices
This review summarizes investigations carried out at the Laboratory of Photochemistry and Energy Conversion (LFCE) in the University of São Paulo dealing with design and characterization of ruthenium(II), rhenium(I) and iridium(III) polypyridine complexes with desired photochemical and photophysical properties in light of the development of optoelectronics
J. Braz. Chem. Soc.. Publicado em: 2020-11
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5. MECANISMO DE EVOLUÇÃO DE HIDROGÊNIO DURANTE A CORROSÃO DA LIGA 2198-T8 EM MEIO CONTENDO CLORETO: UMA ABORDAGEM ELETROQUÍMICA
Corrosion is still one of the most serious and frequent problems in industries. The phenomena involved in the corrosion mechanism of Al-alloys may be explained by formation of galvanic cells between the metal matrix and heterogeneities, such as precipitates, intermetallic phases leading to potential differences and electrochemical reactions. In the cathodic
Quím. Nova. Publicado em: 2020-09
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6. INFLUÊNCIA DA COMPOSIÇÃO DOS NANOFIOS PT-IR/C NA ATIVIDADE CATALÍTICA FRENTE A OXIDAÇÃO ELETROQUÍMICA DE ETANOL EM MEIO ÁCIDO
Carbon-supported platinum-iridium nanowire-shape electrocatalysts containing 20% of metallic loading were synthesized by chemical reduction method using formic acid as a reducing agent and tested towards the oxidation of ethanol in acidic medium. The developed electrocatalysts were synthesized with the following compositions: Pt0.9Ir0.1/C, Pt0.8Ir0.2/C, Pt0.
Quím. Nova. Publicado em: 2020-02
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7. COMPARATIVE STUDY OF TiO2 AND ZnO APPLICATION IN HYBRID SOLAR CELLS USING COPOLYMER P3OT/P3MT
Hybrid inorganic-organic solar cells are an attractive alternative energy source because of their low-cost production and ability to make use of a large amount of solar radiation available. This work aims to evaluate different solar cells composed of TiO2 and ZnO with P3OT/P3MT copolymer. Layers of semiconductor oxides were deposited on transparent fluorine-
Quím. Nova. Publicado em: 02/05/2019
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8. Relationship between Electrochemical Parameters, Cytotoxicity Data against Cancer Cells of 3-Thio-Substituted Nor-Beta-Lapachone Derivatives. Implications for Cancer Therapy
Electrochemical methods are powerful in the characterization and design of redox-modulating agents. We, herein, report the electrochemical investigation, in aprotic medium, of eleven synthetic 3-thio-substituted-nor-beta-lapachones, along with the determination of cytotoxic activity and correspondent selectivity index, against several cancer cell lines and o
J. Braz. Chem. Soc.. Publicado em: 2019-03
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9. Recombination Study of Dye Sensitized Solar Cells with Natural Extracts
Natural dyes can be used in dye sensitized solar cells (DSSCs) to generate low-cost devices, although with low light harvesting because of energy losses from the recombination process. This study investigates recombination reactions in DSSCs with natural dyes extracted from eggplants, plums, and hibiscus flowers. Titanium dioxide films were coated on a fluor
J. Braz. Chem. Soc.. Publicado em: 2019-02
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10. Evaluating the Electrochemical Characteristics of Babassu Coconut Mesocarp Ethanol Produced to Be Used in Fuel Cells
The aim of the present study is to assess the potential of ethanol deriving from the mesocarp of babassu coconut to be used in fuel cells. Babassu ethanol was generated through hydrolysis and fermentation processes. The Pt, PtRh and PtRu electrodes were prepared in carbon Vulcan XC72R through the reduction method and applied as electrocatalysts in ethanol ox
J. Braz. Chem. Soc.. Publicado em: 2018-08
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11. AVALIAÇÃO DA ADSORÇÃO E ESTUDO ELETROQUÍMICO DE CÉLULAS SOLARES PRODUZIDAS COM TiO2 E CORANTE EXTRAÍDO DO HIBISCUS
Dye-sensitized solar cells using natural dyes have lower cost when compared to ruthenium-based dyes. This paper aims to evaluate, electrochemically, solar cells composed of TiO2 with dye extracted from the Hibiscus(var. Sabdariffa) and propose an adsorption model capable of predicting the adsorption mechanism of the dye on the semiconductor surface. The char
Quím. Nova. Publicado em: 2018-05
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12. Optimization of spin-coated electrodes for electrolyte-supported solid oxide fuel cells
ABSTRACT Electrodes for electrolyte-supported solid oxide fuel cells (SOFC's) were fabricated by spin coating. Strontium-doped lanthanum manganite (LSM) cathode and nickel yttria-stabilized zirconia cermet anodes were synthesized and processed for enhanced deposition conditions. The influence of electrode microstructural parameters was investigated by a syst
Matéria (Rio J.). Publicado em: 22/05/2017