Electrochemical Potentials
Mostrando 1-12 de 103 artigos, teses e dissertações.
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1. Electrochemical Behavior of Unusual Dimeric Flavonoids Isolated from Fridericia platyphylla
Brazil has the greatest plant diversity on the planet, distributed in different types of biomes. These plants are important sources of biologically active natural products, which are derived from various drugs marketed worldwide. This paper presents an electrochemical study of three unusual dimeric flavonoids, pharmacologically active, isolated and identifie
J. Braz. Chem. Soc.. Publicado em: 2021-06
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2. Addition of CeO2 Nanorods in PtSn-Based Electrocatalysts for Ethanol Electrochemical Oxidation in Acid Medium
This work describes the preparation of Pt/C, PtxSny/C and PtxSny(CeO2 nanorods/C) nanoparticle catalysts synthesized by the chemical reduction method via sodium borohydride for the ethanol oxidation reaction. Using X-ray diffractogram analysis, it was verified that no alloy formation occurred between platinum (Pt) and tin (Sn). The distribution of the nanopa
J. Braz. Chem. Soc.. Publicado em: 12/08/2019
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3. Corrosion and Micro-abrasive Wear Behaviour of 2524-T3 Aluminium Alloy with PAni-NPs/PSS LbL Coating
In this paper, we present an alternative method to obtain thin films for coating protection on the surface of the AA2524-T3 Al-alloy by using the Layer-by-Layer (LbL) technique. The LbL films were fabricated by alternated immersion of the Al-alloy into a poly(styrene sulfonate) (PSS) and polyaniline nanoparticles (PAni-NPs) solutions, obtaining a PAni-NPs/PS
Mat. Res.. Publicado em: 06/06/2019
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4. Corrosion of galvanic pairs of dental alloys copper base with silver amalgams in artificial saliva
ABSTRACT Galvanic corrosion is a metal dissolution process that occurs when two metals of different electrochemical potential are immersed in an electrolyte causing electrical currents between the metals through the conducting medium. To restore lost or damaged teeth, different alloys are used, leaving the mouth exposed to electrical currents that circulate
Matéria (Rio J.). Publicado em: 20/05/2019
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5. Comportamento da corrosão microbiológica do aço duplex com aplicação de sais de quaternário de amônio
RESUMO A corrosão microbiológica tem causado diversos prejuízos para variados segmentos industriais que utilizam os materiais metálicos em seus sistemas. Uma forma de minimizar e até mesmo controlar os problemas causados pela corrosão microbiológica tem sido a aplicação de biocidas nestes sistemas. Neste trabalho, a corrosão microbiológica do aço
Matéria (Rio J.). Publicado em: 20/05/2019
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6. Caracterización electroquímica de películas de óxido de zinc obtenidas por anodizado en medio alcalino
ABSTRACT Zinc Oxide is a material of particular interest because of its unique optical and electrical properties, which are explored for many applications in optoelectronics and nanoelectronics; and it that can be synthesized economically by the technique of anodization. In this work, the potentiostatic anodization technique was used in dilute NaOH solution,
Matéria (Rio J.). Publicado em: 19/07/2018
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7. Simultaneous Determination of Different Phenolic Compounds Using Electrochemical Biosensor and Multivariate Calibration
Phenolic compounds are important environmental contaminants due to their high toxicity and persistence in the environment. The use of enzyme-based electrochemical biosensors is a simple, sensitive and low-cost alternative for the determination of these pollutants in contaminated waters. However, in most cases, it is impossible to detect specific compounds in
J. Braz. Chem. Soc.. Publicado em: 2018-03
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8. Heat Treatment Effects on ASTM A890/A 890M GR 5A Super Duplex Stainless Steel Passivity
Heat treatment can modify the corrosion resistance of stainless steels. Thus, the corrosion behavior of ASTM A890/A 890M GR 5A super duplex stainless steels (SDSS) has been investigated in aqueous 60,000 ppm NaCl solution by several electrochemical tests. The specimens were aged for 2, 10, 50 and 100 hours at 475 ºC. Potentiodynamic polarization studies sho
Mat. Res.. Publicado em: 22/01/2018
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9. COMPREENSÃO MATEMÁTICA DA DIFUSÃO NO CONTEXTO ELETROQUÍMICO
The aim of this study was to explain in detail the mathematical methods used to deal with diffusion equations, mainly for students and researchers interested in electrochemistry and related areas. Emphasis was placed on the deduction and resolution of diffusion equations, as well as addressing cartesian, spherical and cylindrical coordinates. Different aspec
Quím. Nova. Publicado em: 2016-04
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10. Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
Poly(2,5-dimethoxyaniline) (PDMA) was synthesized using electrochemical polymerization of DMA in oxalic acid. The PDMA film coated onto ITO glass was studied for its chemical structure, morphology, electro-deposition, and electro-activity by FT-IR, TGA, SEM, cyclic voltammetry, and UV-Vis spectrophotometry. The PDMA film showed reversible color changes from
Mat. Res.. Publicado em: 25/08/2015
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11. Simultaneous Determination of Ascorbic Acid, L-Dopa, Uric Acid, Insulin, and Acetylsalicylic Acid on Reactive Blue 19 and Multi-Wall Carbon Nanotube Modified Glassy Carbon Electrode
A trifunctional electrochemical sensor was fabricated for simultaneous determination of ascorbic acid (AA), levodopa (LD), and insulin. This was done by modifying a glassy carbon electrode (GCE) with multi-walled carbon nanotubes and reactive blue 19 (RB-MWCNT-GCE). Cyclic voltammetry was used to investigate the redox properties of this modified electrode. T
J. Braz. Chem. Soc.. Publicado em: 2015-04
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12. Velocidad de corrosión de una aleación base plomo en una solución de ácido sulfúrico a diferentes temperaturas
Car batteries are not only affected by their use and wear but also by other factors such as electrolyte concentration, water loss and temperature that can be exposed, the latter being the most influential factor causing an increase in the corrosion rate of lead alloys (battery components), and affecting their service time. Therefore, for the industry of auto
Matéria (Rio J.). Publicado em: 2014-06