Electrosynthesis
Mostrando 1-12 de 18 artigos, teses e dissertações.
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1. Electrochemical Preparation and Evaluation of Cytotoxic Activity of Methoxyl-oxo-biseugenol, a New Oxidized Derivative of Biseugenol
Electrochemical procedures have emerged as a powerful tool for the synthesis of complex organic molecules including transformation of natural products. In this study, the electrosynthesis of biseugenol in MeOH afforded one new oxidized derivative, which was characterized as methoxyl-oxo-biseugenol (MOB) by nuclear magnetic resonance (NMR) and electrospray io
J. Braz. Chem. Soc.. Publicado em: 2021-05
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2. Formación electroquímica de películas de polipirrol sobre Nitinol a partir de soluciones de ácido sulfosuccínico
ABSTRACT In this work the electrosynthesis of polypyrrole (PPy) on Nitinol from solutions of sulfosuccinic acid (0,25 M) and pyrrole (0,25 M) was studied. The PPy was formed potentiostatically in solutions of pH 1 and 7. As far as we know, this is the first time that the electrodeposition of PPy is carried out in the presence of sulfosuccinic acid. The morph
Matéria (Rio J.). Publicado em: 19/07/2018
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3. Enhancing the Supercapacitive and Superparamagnetic Performances of Iron Oxide Nanoparticles through Yttrium Cations Electro-chemical Doping
A one-pot electrosynthesis platform is reported for fabrication of Y3+ doped iron oxide nanoparticles (Y-IONPs). In this procedure, Y-IONPs are electro-deposited from an additive-free aqueous solution of iron(III) nitrate, iron(II) chloride and yttrium chloride. The analysis data provided by X-ray diffraction (XRD), field emission electron microscopy (FE-SEM
Mat. Res.. Publicado em: 10/07/2018
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4. Electrosynthesis and Characterisation of Polymer Nanowires from Thiophene and its Oligomers
Validating methodology formerly reported, polythiophene electrosynthesised as nanowires from the monomer and some of its oligomers is now described. The work is conducted on a platinum electrode previously modified with a template that tunes the polymer growth inside the confined space of the pores. In addition, it was confirmed that the use of larger chain-
J. Braz. Chem. Soc.. Publicado em: 2015-11
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5. A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE
Electrosynthesis of dimethyl carbonate (DMC) from methanol and carbon monoxide using an Cu(phen)Cl2 catalyst was achieved at room temperature and atmospheric pressure. The catalytic activity of the ligand 1,10-phenanthroline (phen) and the catalytic system were analyzed. The IR characterization results for the complex catalyst showed that copper ions were co
Quím. Nova. Publicado em: 2015-03
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6. Electrosynthesis and optical characterization of poly(p-phenylene), polypyrrole and poly(p-phenylene)-polypyrrole films
Poly(p-phenylene) (PPP), polypyrrole (PPY), and poly(p-phenylene-pyrrole) (PPP-PPY) films were electrochemically synthesized in acetronitrile by cyclic voltammetry. For comparison purposes, the films were characterized by cyclic voltammetry in a monomer-free solution, and their optical responses were also obtained in the UV-VIS range of energy after varying
Mat. Res.. Publicado em: 18/02/2014
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7. Eletrosíntese do metanol e etilenoglicol utilizando eletrodo de difusão de gás / Electrosynthesis of methanol and ethyleneglicol using gas diffusion electrode
O etilenoglicol é um composto orgânico com vasta aplicação em diversos setores da indústria química. Embora as aplicações mais conhecidas sejam como líquido anti-congelante ou na composição de fluídos hidráulicos, o maior consumo deste composto está na fabricação de resinas poliéster saturadas e insaturadas, além de poliuretanos. A produç�
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 18/05/2010
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8. Desinfecção de efluentes tratados com ferrato(IV) / Disinfection of treated effluents with ferrate (VI)
Efluentes tratados de lodos ativados, aeração extendida, de reator seqüencial em batelada, de sistema de lagoas de estabilização e de digestor anaeróbio, UASB, foram submetidos a testes cinéticos e em batelada para verificar as potencialidades e a eficiência de desinfecção pelo íon ferrato(VI). Foi otimizada a produção "in situ" do ferrato(VI) d
Publicado em: 2010
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9. Electrosynthesis and catalytic activity of polymer-nickel particles composite electrode materials
Materiais de eletrodo de compostos poliméricos de níquel foram sintetizados a partir da redução eletroquímica de cátions ou complexos de níquel(II), incorporados por troca iônica ou por complexação, em vários tipos de filmes finos de polipirróis carboxilatos que recobriam eletrodos de carbono preparados por eletropolimerização oxidativa. A ativ
Journal of the Brazilian Chemical Society. Publicado em: 2009
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10. Influência do contra-íon usado na eletrossíntese do polipirrol em sua resposta como biossensor eletroquímico após a imobilização da polifenol oxidase / Influence of counter-ion used in the electrosynthesis of polypyrrole in your response as electrochemical biosensors after polyphenol oxidase immobilization
Neste trabalho, foram fabricados biossensores amperométricos a partir do uso da polifenol oxidase (PFO), obtida do abacate como fonte enzimática, imobilizada em filmes de polipirrol (PPI) e que foram eletrossintetizados em meio de três diferentes eletrólitos de suporte (NaCl e NaClO4 e NaDDS). O método de imobilização enzimática foi o da adsorção,
Publicado em: 2009
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11. Eletrossíntese, caracterização e testes de compósitos de polipirrol e poli(DMcT) sobre fibra de carbono como catodos de baterias secundárias e eletrodos de supercapacitores / Electrosynthesis, characterization and tests of polypyrrole and poly(DMcT) composites on carbon fiber as cathodes of secondary batteries and supercapacitor electrodes
In this work bilayered electrodes made of polypyrrole Ppy and poly(2,5-dimercapto-1,3,4-tiadiazol) poly(DMcT) were produced and characterized on carbon-fiber substrate. To do so, several aspects were investigated: effect of the charge growth (1, 2, 5 and 10 C) on the electrochemical and morphological properties of Ppy electrodeposited on carbon fiber; defini
Publicado em: 2009
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12. Electrosynthesis and characterizations of polypyrrole-2-carboxylic acid for application as amperometric biosensor constructed in microelectrodes / Eletrossíntese e caracterização de filmes de polipirrol-2-ácido carboxílico para uso em biossensores amperométricos construídos em eletrodos miniaturizados
In this work, we present the electrochemical synthesis of a new conducting polymer derived of polypyrrole (PPI) functionalized by carboxylic group, the polypyrrole-2-carboxylic acid, and its application as amperometric transducer in biosensor by use of polyphenol oxidase (PFO). All the steps of syntheses and characterization of the polymer film in microelect
Publicado em: 2009