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1. Sintese da ent-isoagatolactona
The synteses of the enantiomer of isoagatholactona (24), a very interesting natural diterpen from marine invertebrate Spongia officinallis, was carried out using the methyl isocopalate (67) with belongs to the copalic acid (68) by funcionalization of carbon-16. In view, many different methods were used like selenium dioxide, paladium chloride and photooxigen
Publicado em: 1981