Fe Iii Chlorin
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1. Comparative study of hydrocarbon oxygenation with ironchlorins and ironporphyrins as catalysts in homogeneous and heterogeneizated systems / Estudo comparativo da oxigenação de hidrocarbonetos com ferroclorinas e ferroporfirinas como catalisadores em meio homogêneo e heterogeneizados
In this work, the cyclohexane oxidation and the (Z)-cyclooctene epoxidation with iodosylbenzene (PhIO) e H2O2 as oxidants were studied. A comparison between fluorinated FeIIIchlorins and FeIIIporphyrins, [Fe(TFPCMG)]Cl, [Fe(TFPCMGCH3)]Cl2, [Fe(TFPP)]Cl, [Fe(TF4TMAPP)](CF3SO3)5 as catalysts was made either in solution or supported in silica matrices via eletr
Publicado em: 2008