Halide Ions
Mostrando 1-12 de 26 artigos, teses e dissertações.
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1. Electrochemical behavior of Ti and Ti6Al4V in aqueous solutions of citric acid containing halides
This paper reports on an investigation of the electrochemical behavior of Ti grade 2 and Ti6Al4V alloy in aqueous citric acid solutions with pH 2.0 containing halide ions. Voltammetric studies of Ti and the alloy in citric acid, with and without chloride ions, indicate that the Ti and Ti alloy presented a passive behavior in the test solutions used. Pitting
Publicado em: 2010
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2. Electrochemical behavior of Ti and Ti6Al4V in aqueous solutions of citric acid containing halides
This paper reports on an investigation of the electrochemical behavior of Ti grade 2 and Ti6Al4V alloy in aqueous citric acid solutions with pH 2.0 containing halide ions. Voltammetric studies of Ti and the alloy in citric acid, with and without chloride ions, indicate that the Ti and Ti alloy presented a passive behavior in the test solutions used. Pitting
Materials Research. Publicado em: 2006-12
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3. Corrosion inhibition of iron in 0.5 mol L-1 H2SO4 by halide ions
O efeito de inibição de íons haletos, tais como iodeto, brometo e cloreto, na corrosão de ferro em solução 0,5 mol L-1 de H2SO4, e o comportamento da adsorção desses íons na superfície do eletrodo, foram estudados pelos métodos de polarização e de impedância. Foi observada uma inibição de aproximadamente 90% para íons iodeto a 2,5
Journal of the Brazilian Chemical Society. Publicado em: 2006-02
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4. Análise do comportamento iônico em sistemas constituídos por micelas aniônicas, zwitteriônicas ou vesículas catiônicas: uma abordagem teórica por aproximação de campo médio / The analysis of ionic properties in anionic and zwitterionic micelles or cationic vesicles systems: a mean field theoretical approach
Membranes and organelles are structures present in biological systems. Such structures are interfaces between electrolytes. Addressing to the description, interpretation and comprehension of the ionic distribution around the structures an attempt is done is this work analyzing experimental results from the investigation of the following systems: 1) SDS micel
Publicado em: 2006
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5. Novos desenvolvimentos e aplicaÃÃes de mÃtodos de quÃmica quÃntica para compostos de coordenaÃÃo com Ãons lantanÃdeos
Theoretical studies on lanthanide compounds were performed, and divided into three parts: (i) generalization of the Linderberg-Seamans equations for an s-p-d-f basis set; (ii) study of the ligand-to-lanthanide ion charge transfer transitions (LMCT) with the ZINDO98 program using the INDO/S semiempirical hamiltonian and (iii) a study of point charge and charg
Publicado em: 2003
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6. Halide ions as chemical probes for NMR studies of proteins.
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7. Novel Haloperoxidase Reaction: Synthesis of Dihalogenated Products
The enzymatic synthesis of vicinal, dihalogenated products from alkenes and alkynes is described. The enzymatic reaction required an alkene or alkyne, dilute hydrogen peroxide, a haloperoxidase, and molar amounts of halide ions. Vicinal dichloro, dibromo, and diiodo products could be formed. A hydroxyl group on the carbon adjacent to the carbon-carbon double
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8. Kinetics of the iodine- and bromine-mediated transport of halide ions: demonstration of an interfacial complexation mechanism.
Stationary and kinetic experiments were performed on lipid bilayer membranes to study the mechanism of iodine- and bromine-mediated halide transport in detail. The stationary conductance data suggested that four different 1:1 complexes between I2 and Br2 and the halides I- and Br- were responsible for the observed conductance increase by iodine and bromine (
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9. Alternative translocation of protons and halide ions by bacteriorhodopsin.
Bacteriorhodopsin (bR568) in purple membrane near pH 2 shifts its absorption maximum from 568 to 605 nm forming the blue protein bRacid605, which no longer transports protons and which shows no transient deprotonation of the Schiff base upon illumination. Continued acid titration with HCl or HBr but not H2SO4 restores the purple chromophore to yield bRHCl564
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10. High-Chloride Concentrations Abolish the Binding of Adenine Nucleotides in the Mitochondrial ADP/ATP Carrier Family
The ADP/ATP carrier (AAC) is a very effective membrane protein that mediates the exchange of ADP and ATP across the mitochondrial membrane. In vivo transport measurements on the AAC overexpressed in Escherichia coli demonstrate that this process can be severely inhibited by high-chloride concentrations. Molecular-dynamics simulations reveal a strong modific
The Biophysical Society.
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11. Charge density-dependent strength of hydration and biological structure.
Small ions of high charge density (kosmotropes) bind water molecules strongly, whereas large monovalent ions of low charge density (chaotropes) bind water molecules weakly relative to the strength of water-water interactions in bulk solution. The standard heat of solution of a crystalline alkali halide is shown here to be negative (exothermic) only when one
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12. Cl- permeability of human sweat duct cells monitored with fluorescence-digital imaging microscopy: evidence for reduced plasma membrane Cl- permeability in cystic fibrosis.
Salt reabsorption by the human sweat duct is markedly reduced in cystic fibrosis (CF). We used fluorescence-digital imaging microscopy in combination with a halide-specific fluorescent dye [6-methoxy-N-(3-sulfopropyl)quinolinium (SPQ)] to determine if this defective salt reabsorption is referable to a reduced plasma membrane Cl- permeability of the epithelia