In Situ Polymerization
Mostrando 1-12 de 60 artigos, teses e dissertações.
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1. Antimicrobial High-Density Polyethylene (HDPE)/ZnO Nanocomposites Obtained by in situ Polymerization
Nanostructured zinc oxide (ZnO) prepared by combustion in solution was used to obtain nanocomposites. The ZnO particles were characterized by Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), and scanning electron microscopy (SEM), showing crystallite size of 32 nm and a superficial area of 32.6 m2 g-1. Nanocomposites with 1, 3, and 5 wt.% of ZnO in the
J. Braz. Chem. Soc.. Publicado em: 2020-08
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2. Rapid Determination of Vitamins D2 and D3 in Dairy Products by High-Performance Liquid Chromatography after Solid Phase Extraction Based on Polystyrene/Polypyrrole Composite Nanofibers
The detection of vitamin D in complex samples is challenging because of the instability of vitamin D in sample preparation. To resolve this problem, packed-fiber solid-phase extraction (PFSPE) has been successfully developed for the pre-treatment of samples containing vitamin D2 (D2) and vitamin D3 (D3) in dairy products. Based on PFSPE, vitamin D could avoi
J. Braz. Chem. Soc.. Publicado em: 2020-06
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3. Weathering Resistance of Waterborne Polyurethane Coatings Reinforced with Silica from Rice Husk Ash
Abstract: Waterborne polyurethanes (WPUs) are interesting materials for coatings when compared to solvent-based polyurethanes, once that reducing the concentration of volatile organic compounds that are harmful for human health and the environment. However, the WPU has low weathering resistance. In order to improve this behavior among others properties, ino
An. Acad. Bras. Ciênc.. Publicado em: 25/11/2019
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4. Influence of graphene oxide on ‘in situ’ preparation of nanocomposites with polyvinyl butyral
ABSTRACT In this work, polyvinyl butyral (PVB) nanocomposites reinforced with 0.5 to 2.5 wt% of graphene oxide (GO) were synthesized via ‘in situ’ polymerization. PVB was obtained by condensation of hydroxyl groups of polyvinyl alcohol (PVA) with butyraldehyde (BU) Thermogravimetric analyzes (TGA) showed the increase in the thermal conductivity of the na
Matéria (Rio J.). Publicado em: 16/09/2019
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5. Coating of urea granules by in situ polymerization in fluidized bed reactors
Abstract The main objective of the present work is to produce and characterize urea granules coated with polymers prepared with aqueous solutions of acrylic acid and glycerol. Both coating and drying of urea granules were performed in a fluidized bed reactor. Fourier transform infrared spectroscopy analyses indicated the presence of poly(acrylic acid) and ac
Polímeros. Publicado em: 21/03/2019
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6. Development and characterization of gas sensors using thin films of polyaniline as active layer
ABSTRACT This work aimed at the development and characterization of gas sensing devices using thin films of polyaniline (PAni) as active layer, deposited by in situ polymerization. The polyaniline, an intrinsically conductive polymer, was used due to its high sensitivity to gases, low response time and stability, ease of synthesis and low cost. The sensor wa
Matéria (Rio J.). Publicado em: 06/12/2018
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7. Poly (Methyl Methacrylate)-SiC Nanocomposites Prepared Through in Situ Polymerization
In this study, polymeric nanocomposites based on poly(methyl methacrylate) (PMMA) and silicon carbide (SiC) nanoparticles were prepared by radical mass polymerization in the presence of filler. Nanoparticles of SiC with and without surface treatment with organosilane were obtained .The nanocomposites were characterized by X-ray fluorescence (XRF), infrared s
Mat. Res.. Publicado em: 03/09/2018
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8. Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites
Epoxy/CNT and epoxy/CNT/calcium carbonate nanocomposites were produced via in situ polymerization assisted by ultrasonication without solvent and electrical, mechanical, thermal and thermomechanical properties of nanocomposites were evaluated. Epoxy/CNT presented very low percolation threshold, near 0.05 wt % and nanocomposites with higher contents of CNT pr
Mat. Res.. Publicado em: 04/12/2017
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9. Formation of Composite Polyaniline and Graphene Oxide by Physical Mixture Method
ABSTRACT: The development of polyaniline and graphene oxide composites aims to join the unique properties of each material for aerospace applications. The present paper demonstrates an easy and quick method, compared to the ones found in the literature, to obtain a composite made with polyaniline doped with dodecylbenzenesulfonic acid, a combination commonly
J. Aerosp. Technol. Manag.. Publicado em: 2017-03
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10. Electrochromic Properties of Polyaniline-Based Hybrid Organic/Inorganic Materials
Hybrid materials based on polyaniline (PAni) were obtained by in situ polymerization of aniline with chitosan and/or organically modified clay (nanomer I-24) in HCl. The samples were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and direct current (DC) electrical conductivity. Thi
J. Braz. Chem. Soc.. Publicado em: 2016-10
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11. Polypyrrole/Metal Sulphide Hybrid Nanocomposites: Synthesis, Characterization and Room Temperature Gas Sensing Properties
Abstract The present research work explores the room temperature gas sensing ability of hybrid nanocomposites of metal sulphide nanoparticles with polypyrrole (PPy) matrix. Sonochemically synthesized both silver sulphide (Ag2S) and cadmium sulphide (CdS) nanoparticles were mixed in varying ratios with PPy matrix by in-situ oxidative polymerization route. The
Mat. Res.. Publicado em: 01/08/2016
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12. Studying the electrical, thermal, and photocatalytic activity of nanocomposite of polypyrrole with the photoadduct of K3[Fe(CN)6] and diethylenetriamine
Abstract The present work reports the synthesis of nanocomposite of polypyrrole with [Fe(CN)3(dien)].H2O photoadduct via in-situ oxidative chemical polymerisation. Photoadduct was synthesised by irradiating an equimolar mixture of K3[Fe(CN)6] and diethylenetriamine (dien) using Osram photo lamp. The successful synthesis of photoadduct was proved by Elemental
Mat. Res.. Publicado em: 25/07/2016