Microwave Reactor
Mostrando 1-12 de 15 artigos, teses e dissertações.
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1. Expedient Microwave-Assisted Synthesis of Bis(n)-lophine Analogues as Selective Butyrylcholinesterase Inhibitors: Cytotoxicity Evaluation and Molecular Modelling
In the brain of patients with chronic Alzheimer’s disease (AD), the butyrylcholinesterase (BuChE) levels rise while the acetylcholinesterase (AChE) levels decrease. Therefore, development of new selective BuChE inhibitors is of vital importance. Here we present a series of bis(n)-lophine analogues, where two lophine derivatives are connected by a methylene
J. Braz. Chem. Soc.. Publicado em: 2021-06
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2. Synthesis and Antileishmanial Activity of Some Functionalized Peptoids
We describe the microwave-assisted synthesis of thirteen functionalized peptoids and evaluate their in vitro antileishmanial activity against forms of Leishmania (Leishmania) amazonensis promastigotes. Synthesis via the Ugi four-component reaction (Ugi 4CR) reaction furnished the compounds of interest in 55-80% yield; reactions were conducted in a microwave
J. Braz. Chem. Soc.. Publicado em: 23/05/2019
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3. MICROWAVE ACTIVATION OF IMMOBILIZED LIPASE FOR TRANSESTERIFICATION OF VEGETABLE OILS
This work investigated the effect of microwave irradiation (MW) on the ethanolysis rate of soybean and sunflower oils catalyzed by supported Novozyme 435 (Candida antarctica). The effects of tert-butanol, water addition and oil:ethanol molar ratio on transesterification were evaluated under conventional heating (CH), and under optimum reaction conditions (wi
Quím. Nova. Publicado em: 2015-03
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4. Use of heterogeneous catalysts in methylic biodiesel production induced by microwave irradiation
The effect of different heterogeneous catalysts on the microwave-assisted transesterification of sunflower oil for the production of methylic biodiesel in a monomode microwave reactor is described. The experiments were carried out at 70 ºC with a 16:1 methanolsunflower oil molar ratio and different heterogeneous basic and acidic catalysts. The results showe
Quím. Nova. Publicado em: 2014-06
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5. Microwave-assisted synthesis of N-heterocycles and their evaluation using an acetylcholinesterase immobilized capillary reactor
Os etenoditioacetais polarizados são conhecidos como importantes intermediários em muitos processos de síntese. Neste trabalho, reporta-se a anelação livre de metal de transição de 1,1-bis(tiometil)-2-nitroetileno com hidroxilalquilaminas e alquildiaminas. Esta metodologia permite a síntese direta de N-heterociclos tais como imidazolidinas, oxazolidi
J. Braz. Chem. Soc.. Publicado em: 2014-05
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6. Influence of neutral and charged species on the plasma degradation of the stearic acid
In this work, stearic acid (SA) was degraded in an Ar-O2and Ar-H2post-discharge environment created by a plasma reactor with a microwave source and in an Ar, Ar-H2and Ar-O2DC (Direct Current) discharge environment created in a cathode-anode confined system. The afterglow region is useful for understanding the role of the chemically active species (O, O2, H a
Mat. Res.. Publicado em: 28/01/2013
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7. Investigação da reação de Morita-Baylis-Hillman em reator de micro-ondas usando aldeídos aromáticos e isatina como eletrófilos: avaliação da atividade citotóxica em linhagem de células de leucemia promielocítica humanas (HL-60). / Investigation of Morita-Baylis-Hillman Reaction on Microwave Reactor using Aromatic Aldehydes and Isatin as Eletrophiles: Evaluation of Cytotoxic Activity in cell line human promyelocytic leukemia (HL-60).
In this work, we describe the investigation of the Morita-Baylis-Hillman reaction in microwave reactor, under closed vessel conditions to prepare 40 adducts, six novel, using 30 aromatic aldehydes and isatin as electrophiles and acrylonitrile (62a) , methyl acrylate (2), hydroxyethyl acrylate (62b), 2,2-dimethyl-1 ,3-dioxalyl acrylate (62c) and 2,3-dihydroxy
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 14/11/2012
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8. Copolymer of acrylonitrile and vinyl-imidazole from the chemical modification of polyacrylonitrile / Obtenção do copolímero de acrilonitrila e vinil-imidazol a partir da modificação química da poliacrilonitrila
Polymers containing heterocyclic rings such as imidazole, have a great scientific and commercial interest due to its use in several areas. Such polymers can be obtained by chemical modification of polymers such as polyacrylonitrile commercial. Generally, this type of reaction is carried out by conventional heating (thermal). However, more recently, the micro
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 28/02/2012
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9. Síntese da fenitoína assistida por micro-ondas: proposta de aula prática para alunos de graduação
Microwave synthesis is considered a breakthrough in the field of chemistry due to its benefits over conventional heating methods. We describe, for the first time, the total synthesis of phenytoin adapted for a microwave reactor, proposed as an experiment for undergraduate courses. When carried out with microwaves, the synthetic route provided phenytoin in 6
Quím. Nova. Publicado em: 2012
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10. Avaliação de métodos de preparo de amostra para a determinação de halogênios em alumina de alta pureza / Evaluation of sample preparation methods for halogens determination in high-purity alumina
The presence of trace elements in high purity alumina (e.g. halogens) can compromise the final product characteristics. In this work, different sample preparation methods based on alkaline fusion, halogen extraction in water with and without microwave heating, alkaline extraction, microwave-induced combustion and pyrohydrolysis for further halogens determina
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 08/04/2011
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11. Degradação do PMMA através da reação despolimerização uitlizando catalisadores de óxidos mistos
In this work, mixed oxides were synthesized by two methods: polymeric precursor and gel-combustion. The oxides, Niquelate of Lanthanum, Cobaltate of Lanthanum and Cuprate of Lanthanum were synthesized by the polymeric precursor method, and treated at 300 C for 2 hours, calcined at 800 C for 6h in air atmosphere. In gel-combustion method were produced and oxi
Publicado em: 2009
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12. Síntese de nanotubos de carbono orientados e aplicação na produção de pontas de AFM / Oriented growth of carbon nanotubes and application in production of afm Tips
In this work multi walled carbon nanotubes (MWCNT) were obtained. The growth presented high density nanotubes oriented perpendicularly to the substrate, with about 20 m length and diameters between 20 and 60 nm. Catalytic films containing iron were used. These films were deposited from solution of iron nitrate (Fe(NO3)3.9H2O) in ethyl alcohol with concentrat
Publicado em: 2008