Multiresidue
Mostrando 1-12 de 48 artigos, teses e dissertações.
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1. Multiresidue Determination of Endocrine Disrupting Compounds in Sewage Treatment Plants (SPE-HPLC-DAD)
This work focuses on the validation and application of solid phase extraction followed by high-performance liquid chromatography (SPE-HPLC) analysis of important endocrine disruptors compounds (EDC) from different classes in highly complex wastewater matrix. The endocrine disruptors investigated included three different categories: pharmaceuticals (sulfameth
J. Braz. Chem. Soc.. Publicado em: 2020-12
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2. Pesticide Determination in Water Samples from a Rural Area by Multi-Target Method Applying Liquid Chromatography-Tandem Mass Spectrometry
The rises of toxic effects caused by pesticides are of concern. However, Brazilian legislation still needs scientific subsides to improve the water quality requirements. This can be attributed in part to the few existing studies showing the occurrence and levels of multi-residue pesticides. Therefore, the objective of this study was to investigate the presen
J. Braz. Chem. Soc.. Publicado em: 12/08/2019
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3. Multi-Residue Method for Determination of Thirty-Five Pesticides, Pharmaceuticals and Personal Care Products in Water Using Ionic Liquid-Dispersive Liquid-Liquid Microextraction Combined with Liquid Chromatography-Tandem Mass Spectrometry
Ionic liquid-dispersive liquid-liquid microextraction (IL-DLLME) was used for the determination of different chemical classes of analytes for the first time. Limits of quantification (LOQs) ranged from 0.5 to 2.5 µg L-1, and the linearity ranged from the LOQ of each compound to 50 µg L-1. Recoveries ranged from 70 to 120% for the compounds, with relative s
J. Braz. Chem. Soc.. Publicado em: 2018-06
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4. Illicit Drugs, Metabolites and Adulterants in Wastewater: Monitoring Community Drug Abuse in the Brazilian Federal District during the 2014 Soccer World Cup
A multiresidue method was developed to estimate community drug use during two weekends of the 2014 Soccer World Cup via wastewater analyses. Five of the 16 investigated substances were detected in all eight samples. Benzoilecgonine (BE), the major cocaine metabolite, was the most abundant substance (1.9 ± 0.3 to 4.2 ± 0.2 μg L-1) followed by anhydroecgoni
J. Braz. Chem. Soc.. Publicado em: 2017-11
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5. Validation of a LC-MS/MS Multiresidue Methodology Based on a QuEChERS Approach for the Determination of Fluoroquinolones, Sulfonamides and Trimethoprim in Poultry and Porcine Kidney According to the Normative Instruction 24/2009-MAPA
This work involved the validation of a multiresidue method according to the Normative Instruction 24/2009-MAPA for determining 25 analytes, among fluoroquinolones, sulfonamides and trimethoprim in samples of poultry and porcine kidney. The extraction procedure was based on a QuEChERS approach. A liquid chromatography-tandem mass spectrometry (LC-MS/MS) metho
J. Braz. Chem. Soc.. Publicado em: 2017-01
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6. Evaluation of QuEChERS Sample Preparation and Gas Chromatography Coupled to Mass Spectrometry for the Determination of Pesticide Residues in Grapes
An effective analytical method for pesticides multiresidue determination in grape samples was developed and validated. A modified quick, easy, cheap, effective, robust and safe (QuEChERS) method was used to extract the target compounds. Several sorbent materials were tested for the clean-up step using dispersive solid phase extraction (d-SPE) and Florisil®
J. Braz. Chem. Soc.. Publicado em: 2016-09
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7. Optimization of a multi-residue method for 101 pesticides in green tea leaves using gas chromatography–tandem mass spectrometry
ABSTRACT A method for analysis of 101 pesticide residues in tea leaves was developed and validated for the first time. Pure acetonitrile was used as extraction solvent rather than acetonitrile after matrix hydration based on the amount of co-extracts and recoveries performance. During clean-up procedure, primary-secondary amine/graphitized carbon black (500
Rev. bras. farmacogn.. Publicado em: 2016-08
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8. Evaluation of pesticide residues in oranges from São Paulo, Brazil
Pesticides in “PERA” orange samples (N = 57) from São Paulo City, Brazil were assessed and the pesticide intake contribution was estimated for chronic risk assessment. Seventy-six pesticides were evaluated by the gas chromatography multi-residue method, including isomers and metabolites (4.332 determinations). The mean recoveries at the limit of quantif
Food Sci. Technol. Publicado em: 05/02/2016
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9. Monitoring of Pesticide Residues in Surface and Subsurface Waters, Sediments, and Fish in Center-Pivot Irrigation Areas
In this study, the monitoring of pesticide residues, which show potential for environmental contamination, in center-pivot irrigated areas in the Brazilian cerrado, was performed. The pesticides monitored were acephate, atrazine, azoxystrobin, buprofezin, carbofuran, cyproconazole, chlorpyrifos, difenoconazole, diuron, imidacloprid, malathion, methamidophos,
J. Braz. Chem. Soc.. Publicado em: 2015-11
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10. Development of a Multiresidue Method for Pesticide Analysis in Drinking Water by Solid Phase Extraction and Determination by Gas and Liquid Chromatography with Triple Quadrupole Tandem Mass Spectrometry
In this work, a method for multiclass determination of 70 pesticides residues with different properties in drinking water using solid phase extraction (SPE) with polymeric sorbent and determination by gas and liquid chromatography coupled to tandem mass spectrometry (GC-MS/MS and LC-MS/MS) was developed and validated. Different sample volumes, sorbents and e
J. Braz. Chem. Soc.. Publicado em: 2015-10
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11. Single drop microextraction: a sensitive multiresidue method for determination of pesticides in water using GC/ECD
O monitoramento de pesticidas em amostras ambientais em baixas concentrações é necessário devido aos riscos que estes compostos representam a saúde humana e ao meio ambiente. Neste trabalho, o método microextração em gota única (SDME) foi otimizado e validado para a determinação das concentrações traço de oito pesticidas em água utilizando cro
J. Braz. Chem. Soc.. Publicado em: 2014-11
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12. Multiresidue determination of pesticide residues in honey by modified QuEChERS method and gas chromatography with electron capture detection
O mel pode apresentar resíduos de pesticidas devido à contaminação das abelhas durante a coleta de pólen e néctar ou por tratamento das colmeias. Assim, a determinação de resíduos de pesticidas em mel é de grande importância, apesar da dificuldade devido à complexidade da matriz. Neste estudo, um novo método para a determinação de pesticidas d
J. Braz. Chem. Soc.. Publicado em: 2014-08