Nuclear Resonance Fluorescence
Mostrando 1-12 de 77 artigos, teses e dissertações.
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1. Synthesis of Conjugated Molecules Based on Dithienopyrrole Derivatives and Pyrene as Chemosensor for Mesotrione Detection
The conjugated molecules based on pyrene and dithienopyrrole derivatives including 4-(2-ethylhexyl)-2-(pyren-1-yl)-4H-dithieno[3,2-b:2’,3’-d]pyrrole (EP4HP) and 4-(2-ethylhexyl)-2,6-di(pyren-1-yl)-4H-dithieno[3,2-b:2’,3’-d]pyrrole (EDP4HP) have been successfully synthesized via C-H direct arylation reaction. The structures of these conjugated molecul
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Blue Glow Sticks: Cinnamic Acids and Arylacrylonitriles with Liquid-Crystalline Properties and Highly Fluorescent
Five new π-conjugated chromophores derived from acrylic acid and acrylonitrile were synthesized and their thermal and photophysical behaviors were analyzed. They were designed and synthesized through Knoevenagel condensations between arylacetylenebenzaldehydes and a methylene group activated from cyanoacetic and malonic acids. The characterization of the ta
J. Braz. Chem. Soc.. Publicado em: 2021-01
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3. Reordering of Depolymerized Silicates as Adsorbents for Large Nitrogen Compounds
The adsorption capacities of two synthesized zeolites (crystalline ZSM-5 and semi-crystalline faujasite Y) for a mixture of indole, quinoline and carbazole were studied. The different samples obtained show different crystalline degree, mesoporosity and Si/Al ratios. The synthesis procedure is based on the simultaneous depolymerization of a mixture of high su
J. Braz. Chem. Soc.. Publicado em: 2021-01
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4. A Highly Selective Fluorescent Chemosensor for Al3+ Based on 2,2’:6’,2”-Terpyridine with a Salicylal Schiff Base
Two 2,2’:6’,2”-terpyridine-based Schiff bases (TPySSB and TPySB) have been synthesized. The TPySSB shows remarkable selective ‘off-on’ fluorescence for Al3+ in combination with photoinduced electron transfer (PET) mechanism and C=N isomerization mechanism. Chemosensor TPySSB binds Al3+ in a 1:2 ratio with an association constant 6.8 × 105 (correla
J. Braz. Chem. Soc.. Publicado em: 2020-09
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5. A Simple Fluorescent Chemosensor for Detection of Zinc Ions in Some Real Samples and Intracellular Imaging in Living Cells
A new designed fluorescent chemosensor TYMN ((E)-1-((thiazol-2-ylimino)methyl)naphthalen-2-ol) for highly sensitive and selective tracing of trace amount of Zn2+ ions in some real samples was synthesized and characterized. The sensor TYMN can detect Zn2+ ions via fluorescence enhancement with a high selectivity over a wide range of metal ions, especially Cd2
J. Braz. Chem. Soc.. Publicado em: 2020-08
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6. Residue-Based CaO Heterogeneous Catalysts from Crab and Mollusk Shells for FAME Production Via Transesterification
The production of fatty acid methyl esther (FAME) via transesterification was studied, assessing the influence of CaO heterogeneous catalysts obtained from four different fishery residues: sururu, crab, clam and mussel. Characterization and properties of the residues were obtained via thermogravimetric analysis, X-ray diffraction, X-ray fluorescence, Fourier
J. Braz. Chem. Soc.. Publicado em: 2020-04
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7. Water-Soluble Benzazole Dyes Fluorescent by ESIPT: Structural Characterization, Photophysical Properties and Its Application as a Probe for Direct Staining of Helminths
A series of four water-soluble benzazole dyes that emit fluorescence by the excited state intramolecular proton transfer (ESIPT) mechanism were structurally characterized by Fourier transform infrared spectroscopy (FTIR), 1H and 13C nuclear magnetic resonance (NMR) attached proton test (APT) and mass spectrometry. Their photophysical properties were systemat
J. Braz. Chem. Soc.. Publicado em: 2019-03
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8. Matéria Evaluation of zinc oxide nanoparticles influence on hydrophilic polymer matrix systems
ABSTRACT Hydrophilic polymer matrix systems (HPMSs) are a highly relevant tool for drugs delivery whose bioavailability is impaired by low hydrosolubility. Besides this, when associated with nanoparticles these systems can provide better control over release profile of the active drug, maintaining the posology. Since polyvinylpyrrolidone (PVP) and zinc oxide
Matéria (Rio J.). Publicado em: 06/12/2018
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9. Syntheses, Experimental and Theoretical Studies on Absorption/Emission Properties of Pyrazoline-Containing Aryl/Methoxynaphthyl Substituents
5-Aryl-3-(2-methoxynaphthalen-6-yl)-1-phenylpyrazoline derivatives were synthesized starting from (E)-1-(3-aryl)-(2-methoxynaphthalen-6-yl)-prop-2-en-1-one and phenylhydrazine. The compounds were characterized by 1H and 13C nuclear magnetic resonance (NMR), elemental analyses and mass spectrometry. Some compounds showed promising luminescence properties in s
J. Braz. Chem. Soc.. Publicado em: 2018-06
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10. Synthesis and Photophysical Characterization of Proton Transfer-Based Thiourea Derivatives: Potential Application as Colorimetric Naked-Eye Chemosensor for Fluoride Detection in Solution
Two new thiourea derivatives were synthesized through the reaction of photoactive aminohydroxybenzazoles and p-isothiocyanate benzoic acid via nucleophilic addition reaction. The compounds were characterized using high resolution mass spectrometry with eletrospray ionization (HRMS-ESI), Fourier transform infrared (FTIR), 13C and 1H nuclear magnetic resonance
J. Braz. Chem. Soc.. Publicado em: 2017-09
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11. Catechol Oxidase, Phosphatase-Like Activity, DNA/BSA Binding Studies of RuII Complexes of S-Allyldithiocarbazate: Synthesis and Spectral Studies
New ruthenium(II) complexes with formulae [RuCl(CO)(PPh3)2L1] and [RuCl(CO)(PPh3)2L2] (L1 = S-allyl-4-methoxy benzylidene hydrazine carbodithioate, L2 = S-allyl-1-naphthylidene hydrazine carbodithioate) have been synthesized and characterized by elemental analysis, Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR), UV-Vis, electrospray ioni
J. Braz. Chem. Soc.. Publicado em: 2017-08
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12. Synthesis and Photophysical Characterization of Novel ESIPT Triazinyl-Benzazole Derivatives
In this work, the synthesis, characterization and photophysical study of new derivatives of triazinyl-benzazoles with fluorescence by excited-state intramolecular proton transfer (ESIPT) are presented. It regards the synthesis of cyanuric chloride with different 2-(2’-hydroxyphenyl) benzazoles, two quite attractive groups from the synthetic and technologic
J. Braz. Chem. Soc.. Publicado em: 2015-12