Organic Inorganic Hybrids
Mostrando 1-12 de 14 artigos, teses e dissertações.
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1. Geopolymer/PEG Hybrid Materials Synthesis and Investigation of the Polymer Influence on Microstructure and Mechanical Behavior
Geopolymers are aluminosilicate inorganic polymers, obtained from the alkali activation of powders containing SiO2+Al2O3>80wt%, mainly proposed as environmentally friendly building materials. In this work, metakaolin-based geopolymers have been prepared and a water-soluble polymer, polyethylene glycol (PEG), has been added in different percentages to obtain
Mat. Res.. Publicado em: 25/08/2015
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2. Inorganic-organic hybrids originating from organosilane anchored onto leached vermiculite
The reactivity of clay minerals leached in grafting reactions was investigated. Precursor solids were prepared by treating the sodium vermiculites with nitric acid solutions at several concentrations. The lixiviation produced the restructured porous solids with surface area over a wide range, varying from 133 to 673 m² g- 1. The sodium and lixiviated vermic
Mat. Res.. Publicado em: 21/05/2013
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3. Inorganic-organic hybrids based on poly (ε-Caprolactone) and silica oxide and characterization by relaxometry applying low-field NMR
Poly (ε-caprolactone) (PCL) based hybrids containing different amounts of modified (Aerosil® R972) and unmodified (Aerosil® A200) silica oxide were prepared employing the solution method, using chloroform. The relationships of the amount of nanofillers, organic coating, molecular structure and intermolecular interaction of the hybrid materials were invest
Mat. Res.. Publicado em: 25/09/2012
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4. Multi walled carbon nanotubes nanocomposites with hybrid epoxy-copolysilsesquioxanes matrices / Nanocompósitos de nanotubos de carbono de paredes múltiplas com matrizes híbridas epóxido-copolissilsesquioxanos
Este trabalho teve por objetivo a síntese de oligômeros de silsesquioxanos contendo grupos amino e fenil, e a posterior formação de um híbrido orgânico-inorgânico pela reação dos grupos amino do precursor silsesquioxano com o anel epoxídico da resina diglicidil éter de bisfenol A (DGEBA). O processo sol-gel adotado na síntese dos oligômeros demo
Publicado em: 2010
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5. Hibridos inorganico-organicos nanoestruturados e termoquimica da interação cation-centros basicos / Inorganic-organic nanostructured hybrids and thermochemistry of cation-basic center interaction
Este trabalho descreve a preparação, caracterização e aplicação de novos materiais híbridos inorgânico-orgânicos nanoestruturados, obtidos a partir do processo de funcionalização da superfície lamelar de derivados do RUB-18, a forma ácida do material, H-RUB-18, e a forma intercalada com moléculas orgânicas polares, CTA-RUB-18. Para esse proces
Publicado em: 2009
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6. Polyphosphate hybrid materials: photochemistry, (di)electric characterization and its application in electrochemical capacitors / Materiais hÃbridos de polifosfatos: fotoquÃmica, caracterizaÃÃo (di)elÃtrica e sua utilizaÃÃo em capacitores eletroquÃmicos
The synergy between the properties of two substances, an organic and another inorganic, can be obtained in a single material by the sol-gel process. The low temperature processing allow the incorporation of organic substances in inorganic matrices. These hybrid materials can have covalent interactions between host and guest (C1), or weak interactions, like v
Publicado em: 2008
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7. PROPRIEDADES TÉRMICAS, DIELÉTRICAS E VIBRACIONAIS DE ORMOSIL S BASEADOS EM PDMS E TEOS DOPADOS COM MDS / THERMAL, DIELECTRIC PROPERTIES AND VIBRACIONAIS OF ORMOSIL S BASED IN DOPED PDMS AND TEOS WITH MDS
In this work have been investigated the dielectric and vibrational properties of the ORMOSIL membranes based on PDMS and TEOS doped with MDS using the Dierential Scanning Calorimetry (DSC), impedance, Raman and infrareds spectroscopy technics. Such membranes are hybrid organic-inorganic materials with potential application in PEMFC (Proton Exchange Membrane
Publicado em: 2008
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8. SÃntese e estudo espectroscÃpico de complexos de Ãons lantanÃdeos incorporados em materiais hÃbridos orgÃnicos-inorgÃnicos
In this work two new europium and gadolinium b-diketonate complexes, [Ln(btfa)3(4,4 -bpy)(EtOH)] (Ln = Eu, Gd; 4,4 -bpy = 4,4 -bipyridine; btfa = 4,4,4- trifluoro-l-phenyl- 1,3-butanedione), were prepared and incorporated into a organicinorganic hybrid material. The general formulae of these complexes were confirmed by X-rays single crystal data and elementa
Publicado em: 2007
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9. Structure and properties of Ti4+-ureasil organic-inorganic hybrids
Guias de luz planares foram obtidos a partir de um sol de um novo híbrido Ti4+-acetilacetona (acac)-Ureasil depositado na forma de filmes finos sobre substratos de vidro. A estrutura foi investigada por medidas espectroscópicas (absorção no infravermelho, fotoelétrons de raios-X e espalhamento Raman) e espalhamento de raios-X a baixos ângulos (SAXS). P
Journal of the Brazilian Chemical Society. Publicado em: 2006-06
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10. Characterization of organic-inorganic hybrid coatings for corrosion protection of galvanized steel and electroplated ZnFe steel
The development of hybrids materials has been extensively investigated in recent years. The combination of a wide variety of compositions and production processes had permitted the use of these materials in different applications like coatings for corrosion protection of metals. In this work organic-inorganic hybrid materials have been prepared from the hydr
Materials Research. Publicado em: 2006-03
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11. Filmes híbridos orgânico-inorgânicos a partir de óleo de soja funcionalizado
Organic-inorganic hybrids materials can be prepared by the sol-gel process and have applications in biomaterials, catalysis, optics, membranes, chromatography, electrochemistry and coatings. Vegetable oils can be used as organic component for the preparation of these materials and, as they are biodegradable and obtained from natural and renewable sources, th
Publicado em: 2006
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12. Synthesis and characterization of organic-inorganic hybrids formed between conducting polymers and crystalline antimonic acid
Neste trabalho são relatadas e discutidas a síntese e a caracterização de dois materiais híbridos orgânico-inorgânico, formados entre o ácido antimônico cristalino (AAC), como fração inorgânica, e dois polímeros condutores (polipirrol e polianilina) como fração orgânica. Os híbridos foram obtidos a partir da polimerização oxidativa in situ
Journal of the Brazilian Chemical Society. Publicado em: 2001-08