Organic Ligands
Mostrando 1-12 de 58 artigos, teses e dissertações.
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1. Supramolecular Approach in Energy Conversion Devices
This review summarizes investigations carried out at the Laboratory of Photochemistry and Energy Conversion (LFCE) in the University of São Paulo dealing with design and characterization of ruthenium(II), rhenium(I) and iridium(III) polypyridine complexes with desired photochemical and photophysical properties in light of the development of optoelectronics
J. Braz. Chem. Soc.. Publicado em: 2020-11
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2. New Metal-Organic Systems with a Functionalized Oxamate-Type Ligand and MnII, FeII, CuII and ZnII
Four new complexes of formula [Fe(H2pcpa)2(H2O)2] (1), {[Mn(Hpcpa)(H2O)3]•1/2H2O}n (2), {[Zn(Hpcpa)(H2O)3]•1/2H2O}n (3) and [Cu2(Hpcpa)2(bipy)2]•8H2O (4) [H3pcpa = N-(4-carboxyphenyl)oxamic acid; bipy = 2,2¢-bipyridine] have been synthesized and their structures determined by X-ray diffraction. The structure of 1 consists of mononuclear iron(II) units
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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3. OS LANTANÍDEOS NAS REDES METALORGÂNICAS: UMA NOVA CLASSE DE MATERIAIS POROSOS
Lanthanoid organic frameworks (LOFs) stand out as an important class of functional materials. The possibility to employ a great range of metals and ligands lead to the formation of varied and highly porous structures, with diverse applications. The presence of lanthanoid ions favours the improvement of the optical, magnetic and redox properties of MOFs. This
Quím. Nova. Publicado em: 2018-06
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4. Synthesis and Characterization of Non-Linear Optical Crystal of Manganese Mercury Thiocyanate Glycol Monomethyl Ether
The design and synthesis of organic nonlinear optical (NLO) crystals are a promising area of current research in materials science. Organic materials are found to possess better non linear optical properties when compared to inorganic materials. Recently, there has been a widespread interest in the metal-organic coordination compounds, which are a combinatio
Mat. Res.. Publicado em: 30/11/2017
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5. Two novel Co(II) complexes with two different Schiff bases: inhibiting growth of human skin cancer cells
Using two flexible Schiff bases, H2L1 and H2L2, two new cobalt II (Co(II))-coordination compounds, namely, Py3CoL1 (1) and Py3CoL2 (2) (Py=pyridine, L1=3,5-ClC6H2(O)C=NC6H3(O)-4-NO2, L2=3,5-BrC6H2(O)C=NC6H3(O)-4-NO2) have been synthesized under solvothermal conditions. Single crystal X-ray structural analysis revealed that compounds 1 and 2 are both six-coor
Braz J Med Biol Res. Publicado em: 03/07/2017
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6. Redes metalorgânicas e suas aplicações em catálise
Metal-organic frameworks (MOFs) form a new class of materials with well-defined yet tunable properties. These are crystalline, highly porous and exhibit strong metal-ligand interactions. Importantly, their physical and chemical properties, including pore size, pore structure, acidity, and magnetic and optical characteristics, can be tailored by choosing the
Quím. Nova. Publicado em: 2014
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7. Catálise assimétrica no Brasil: desenvolvimento e potencialidades para o avanço da indústria química brasileira
The preparation of enantiomerically pure or enriched substances is of fundamental importance to pharmaceutical, food, agrochemical, and cosmetics industries and involves a growing market of hundreds of billions of dollars. However, most chemical processes used for their production are not environmentally friendly because in most cases, stoichiometric amounts
Quím. Nova. Publicado em: 2013
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8. Chelated minerals for poultry
Organic minerals have been subject of an increasing number of investigations recently. These compounds can be considered the most significant event regarding commercial forms of minerals targeting animal supplementation in the last decades. Minerals, especially metals, are usually supplemented in poultry feeds using cheap saline sources and have never requir
Publicado em: 2010
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9. Comparação da labilidade de metais empregando voltametria, difusão em filmes finos por gradiente de concentração (DGT) e modelo computacional
Speciation of metals in a synthetic freshwater was comparatively evaluated using Anodic Stripping Voltammetry, Diffusive Gradients in Thin Films and a Chemical Equilibrium Model. The labile fractions of Cu and Zn quantified by DGT were similar to the ones measured by ASV. The labile species of Cd and Pb could not be determined by both experimental methods du
Química Nova. Publicado em: 2010
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10. Eficiência agronômica de fertilizantes fosfatados em solos com diferentes capacidades de adsorção de fósforo e teores de matéria orgânica / Agronomic efficiency of phosphate fertilizers in soils with different capacity of phosphate adsorption and organic matter levels
Tropical soils highly intemperized show increased capability on phosphorus (P) adsorption. Several factors may influence P adsorption in such soils, but special attention must be paid on the organic matter level. Mechanisms involved in this process are related to the release of organic acids derived from the decomposition of the organic matter, which may eit
Publicado em: 2010
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11. Estudo sobre o hidróxido de potássio no processo de produção industrial de poliol poliéter
Metallic ions may interact with polyether polyols giving macromolecular complexes. From this approach, it was investigated the interaction of cationic potassium with polyether polyols by means of several techniques in order to proof complexation as well as its ocurrence. The industrial synthesis of polyether polyols does not result in a pure product but give
Publicado em: 2010
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12. Utilização do D-manitol em síntese orgânica
D-mannitol is used in several fields including food, pharmaceuticals, cosmetics and textiles being an important carbohydrate found widespread in nature. Due to its chirality, it is largely used in organic synthesis with several applications, such as ligands, polymers, chiral pool, for preparation of small chiral building blocks, key intermediates in total sy
Química Nova. Publicado em: 2009