Organic Reaction Mechanisms
Mostrando 1-12 de 26 artigos, teses e dissertações.
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1. DESVENDANDO UM CASO: QUANDO ESTUDANTES SE TORNAM PERSONAGENS DE UMA HISTÓRIA NA DISCIPLINA DE QUÍMICA ORGÂNICA EXPERIMENTAL
Being part of the Pharmacy course curriculum, Organic Chemistry emphasizes the fundamentals of Organic Synthesis, reaction mechanisms, as well as the methods for separation, purification and identification of organic compounds. However, students do not always realize the direct association between this knowledge and their future working field. In an effort t
Química Nova. Publicado em: 2022
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2. Dificuldades no ensino e na aprendizagem de química orgânica do ensino superior - estudo de caso em duas Universidades Federais
This research investigates difficulties associated to the curricular component Organic Chemistry I based on a study case of Chemistry undergraduate courses (Bachelor and Teachers education) in two Federal Universities in the Brazilian South region. The analytical process integrated official documents of the courses (pedagogic projects, students’ grades), q
Quím. Nova. Publicado em: 2021-06
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3. DESENVOLVIMENTO NOS MÉTODOS DE GLICOSILAÇÃO: UMA CHAVE PARA ACESSAR SUAS APLICAÇÕES NA SÍNTESE DE MOLÉCULAS BIOATIVAS
Glycosylation reaction is an important class of reactions in organic chemistry, and the development of the method contributes to the synthesis of many biologically active compounds containing various glycoside bonds. Is arguably the most important, albeit challenging, reaction in the field of carbohydrate chemistry. Examples of the products of glycosylation
Quím. Nova. Publicado em: 2021-04
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4. HUISGEN AND HIS ADVENTURES IN A PLAYGROUND OF MECHANISMS AND NOVEL REACTIONS
The death of professor Rolf Huisgen (1920-2020) was announced on March 26th 2020, in the midst of the COVID-19 pandemic. Professor Huisgen was professor emeritus at the University of Munich in Germany, and studied in detail the mechanism of the 1,3-dipolar cycloaddition reaction, significantly expanding its scope. Even though he did not discover this reactio
Quím. Nova. Publicado em: 2021-02
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5. ELABORAÇÃO E USO DE ANIMAÇÕES COMO ESTRATÉGIA PARA O ENSINO DE MECANISMOS DAS REAÇÕES ORGÂNICAS
The Chemistry of organic compounds is present in many aspects of life on the planet. In addition to many substances in our body being organic compounds, the energy matrix is based on burning fossil fuels, the biodiesel industry is also linked to organic reactions as well as the pharmaceutical industry. However, Organic Reaction Mechanisms is considered one o
Quím. Nova. Publicado em: 2020-09
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6. BDD-Electrolysis of Oxalic Acid in Diluted Acidic Solutions
Boron doped diamond films (BDD) are the most studied electrocatalytic materials and their efficiency for removing organic compounds is attributed to their ability to produce a large amount of hydroxyl radicals by the electrolysis of water. However, some organic compounds are easy to degrade than others, as well as they also interact with BDD surface. Thus, i
J. Braz. Chem. Soc.. Publicado em: 04/07/2019
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7. Precipitación de uranio a partir de licores alcalinos
ABSTRACT In Argentina there is uranium with abundant organic matter and variety in quantity of sulfides and carbonates which act as cement or sealing joints. The latter minerals modify directly the choice of metal leaching process for the concentration of uranium. The most beneficial selected process turns out to be the alkaline leaching. Once this process h
Matéria (Rio J.). Publicado em: 19/07/2018
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8. Wet oxidation of glycerol into fine organic acids: catalyst selection and kinetic evaluation
The liquid phase oxidation of glycerol was performed producing fine organic acids. Catalysts based on Pt, Pd and Bi supported on activated carbon were employed to perform the conversion of glycerol into organic acids at 313 K, 323 K and 333 K, under atmospheric pressure (1.0 bar), in a mechanically agitated slurry reactor (MASR). The experimental results ind
Braz. J. Chem. Eng.. Publicado em: 2014-12
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9. Otimização do processo de mineralização de compostos orgânicos utilizando sistemas eletro-Fenton e fotoeletro Fenton por irradiação UV artificial e solar
OPTIMIZATION OF THE MINERALIZATION PROCESS OF ORGANIC COMPOUNDS USING ELECTRO-FENTON AND PHOTO-FENTON SYSTEMS BY ARTIFICIAL AND SOLAR UV IRRADIATION Electrochemical advanced oxidation processes based on the Fentons reaction, such as electro-Fenton (EF) and photoelectro-Fenton (PEF) using artificial and solar UV irradiation were employed in the treatment of e
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 30/09/2011
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10. Efeito da ativação local do receptor capa opióide no extravasamento plasmático e migração de neutrófilos na articulação temporomandibular de ratos / Effect of local activation of opioid kappa receptors in plasma extravasation and neutrophil migration in the temporomandibular joint in rats
In an attempt to decrease central side effects associated with the use of opioids, some strategies have been developed by targeting peripheral opioid receptors. In this context, kappa opioid receptors are of major interest, since, in contrast to other opioid receptors, their activation is not associated with potent peripheral side effects. We have recently d
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 29/07/2011
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11. Estudo sobre a redução de Fe3+ por extratos aquosos de cultivos de Ceriporiopsis subvermispora sobre madeira e sua relação com a peroxidação de lipídeos / Studies on Fe3+ reduction by aqueous extracts recovered from cultures of Ceriporiopsis subvermispora on wood and its correlation with lipid peroxidation
The present work is inserted in a broad study aiming to understand the chemical and biochemical mechanisms involved in wood biodegradation by Ceriporiopsis subvermispora. Particularly, the relationship between the Fe3+-reducing activity present in aqueous extracts recovered from Ceriporiopsis subvermispora cultures on wood with the initiation of linoleic aci
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 12/02/2009
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12. Mechanistic study of the synthesis of alquilfenilselenetos, the reaction type Zn-Barbier aqueous vehicle / Estudo mecanístico da síntese de alquilfenilselenetos, pela reação tipo Zn-Barbier em meio aquoso
Alkyl phenyl selenides are versatile synthetic intermediates. In addition to the traditional methods, a method of synthesis was developed by Bieber by reacting diphenyl diselenide with organic halides using zinc dust in water / acetonitrile for a wide range of substrates. The lack of precedents in the understanding of this reaction limits the choice of the c
Publicado em: 2009