Organic Syntheses
Mostrando 1-12 de 21 artigos, teses e dissertações.
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1. Impact of continuous flow chemistry in the synthesis of natural products and active pharmaceutical ingredients
ABSTRACT We present a comprehensive review of the advent and impact of continuous flow chemistry with regard to the synthesis of natural products and drugs, important pharmaceutical products and definitely responsible for a revolution in modern healthcare. We detail the beginnings of modern drugs and the large scale batch mode of production, both chemical an
An. Acad. Bras. Ciênc.. Publicado em: 2018
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2. Organic Synthesis: New Vistas in the Brazilian Landscape
ABSTRACT In this overview, we present our analysis of the future of organic synthesis in Brazil, a highly innovative and strategic area of research which underpins our social and economical progress. Several different topics (automation, catalysis, green chemistry, scalability, methodological studies and total syntheses) were considered to hold promise for t
An. Acad. Bras. Ciênc.. Publicado em: 2018
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3. Enzymatic potential of heterotrophic bacteria from a neutral copper mine drainage
Abstract Copper mine drainages are restricted environments that have been overlooked as sources of new biocatalysts for bioremediation and organic syntheses. Therefore, this study aimed to determine the enzymatic activities (esterase, epoxide hydrolase and monooxygenase) of 56 heterotrophic bacteria isolated from a neutral copper mine drainage (Sossego Mine,
Braz. J. Microbiol.. Publicado em: 2016-12
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4. Synthesis and Characterization of Al-TON Zeolite Using a Dialkylimizadolium as Structure-Directing Agent
In this work, the synthesis of zeolites using 1-butyl-3-methylimidazolium chloride [C4MI]Cl as a structure-directing agent was investigated. The organic cation shows effectiveness and selectivity for the syntheses of TON zeolites under different reaction conditions compared to the traditional structure-directing agent, 1,8-diaminooctane. The 1-butyl-3-methyl
Mat. Res.. Publicado em: 07/11/2016
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5. SÍNTESES TOTAIS NO BRASIL EMPREGANDO ACOPLAMENTOS CRUZADOS MEDIADOS POR PALÁDIO
This article aims to show the selected total syntheses of organic compounds conducted by Brazilian researchers, performed in Brazil, which have employed a palladium catalyzed cross-coupling reaction as key step. We intended to thus create an account, although restricted to the use of palladium, showing the evolution and current state of art of Synthetic Orga
Quím. Nova. Publicado em: 2016-08
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6. Plant growth promoting capability and genetic diversity of bacteria isolated from mud volcano and lime cave of Andaman and Nicobar Islands
Twenty four bacterial strains from four different regions of mud volcano and lime cave were isolated to estimate their diversity, plant growth promoting and biocontrol activities to use them as inoculant strains in the fields. An excellent antagonistic effect against four plant pathogens and plant growth promoting properties such as IAA production, HCN produ
Braz. J. Microbiol.. Publicado em: 2014-12
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7. Síntese de cristais líquidos derivados do nitroazobenzeno: uma proposta de síntese multi-etapas aplicada às aulas de química orgânica experimental
We describe a synthetic route consisting of five steps from aniline to obtain liquid crystal compounds derived from nitroazobenzene. Syntheses were performed during the second half of the semester in organic chemistry laboratory classes. Students characterized the liquid crystal phase by the standard melting point techniques, differential scanning calorimetr
Quím. Nova. Publicado em: 2014
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8. Nanoporous materials: pillared clays and regular silicas as an example of synthesis and their porosity characterization by X-ray diffraction
Because of their practical applications, porous materials attract the attention of undergraduate students in a way that can be used to teach techniques and concepts in various chemistry disciplines. Porous materials are studied in various chemistry disciplines, including inorganic, organic, and physical chemistry. In this work, the syntheses of a microporous
Quím. Nova. Publicado em: 2014
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9. Resolução do ibuprofeno: um projeto para disciplina de química orgânica experimental
A practical and didactic sequence of experiments was proposed to illustrate the stereochemistry concept, optically active compounds, resolution of racemates, and use of the NMR technique, including 2D-COSY for identification of organic compounds, on a laboratory course for undergraduate students. The sequence was: extractions of racemic ibuprofen and chiral
Quím. Nova. Publicado em: 2012
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10. Synthesis and strategic aplications of some neurotoxins produce for cyanobacteria / Síntese e aplicações estratégicas de algumas neurotoxinas produzidas por cianobactérias
As cianobactérias apresentam distribuição variada e podem ocorrer desde as regiões frias do ártico até os trópicos, em corpos dágua doce e no ambiente marinho. Algumas espécies de cianobactérias produzem compostos com conhecida toxidade, podendo causar efeitos deletérios em seres humanos e animais. Entre estes compostos estão os com atividade neu
Publicado em: 2009
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11. Vladimir Prelog e a estereoquímica das moléculas orgânicas: um centenário de nascimento
The Croatian chemist Vladimir Prelog shared in 1975 the Nobel Prize in chemistry with J. W. Cornforth for his research into the stereochemistry of organic molecules and reactions. His studies gave new horizons to the comprehension of steric effects on the reactivity of medium-sized rings, to conformational analysis and to the stereospecificity associated to
Química Nova. Publicado em: 2007-08
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12. Multibiorreações e suas aplicações para as sinteses de compostos enantiomericamente puros / Multibioreactions applied to the syntheses of enantiomerically pure compounds
The utilization of enzymes for organic compound transformations is an alternative to classical syntheses. Enzymes are used as biocatalysts for the syntheses in vitro of asymmetric compounds because they are intrinsically chiral and result in high catalytic efficiency. In front of the biodiversity of existing microorganisms in Nature and of the necessity to d
Publicado em: 2006