Organophosphates
Mostrando 1-12 de 64 artigos, teses e dissertações.
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1. A Physical Study to Explain Response Differences between the BID and FID Detectors for PAHs and Pesticides
The dielectric barrier discharge ionization detector (BID) is one of the most modern detectors commercially available for gas chromatography (GC). Its technology based on the sample ionization through the energy released from the helium plasma generation process gives it the ability to act as a universal detector and a greater response to various types of co
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Stability Analyses by HPLC-MS of Guanitoxin Isolated from Sphaerospermopsis torques-reginae
Guanitoxin (GNT) is a natural organophosphate produced by some species of freshwater cyanobacteria, which inhibits the active site of acetylcholinesterase, preventing the hydrolysis of cholinesterases and consequently causing serious disturbances in the neuromuscular system. Despite having a chemical structure like synthetic organophosphates, there is still
J. Braz. Chem. Soc.. Publicado em: 2021-08
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3. Are Imidazoles Versatile or Promiscuous in Reactions with Organophosphates? Insights from the Case of Parathion
Is the broad mechanistic versatility of imidazole towards organophosphates (OPs), that has inspired many catalysts and sensors, beneficial? Herein, a thorough analysis is given seeking to unravel this puzzle. For OPs from the P=O family, imidazole attacks the phosphorus atom exclusively (N-phosphorylates). With the P=S family which are less reactive, an unus
J. Braz. Chem. Soc.. Publicado em: 21/10/2019
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4. Occupational exposure to pesticides and hematological alterations: A survey of farm residents in the South of Brazil
Resumo O objetivo deste estudo foi investigar a associação entre a exposição a organoclorados (OC) e agrotóxicos não persistentes e os parâmetros hematológicos em uma população agrícola de Farroupilha-RS. Foi utilizado um questionário para coletar informações sobre fatores sociodemográficos e de estilo de vida, duração, frequência e tipo de
Ciênc. saúde coletiva. Publicado em: 27/06/2019
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5. ORGANOCLORATED AND ORGANOPHOSPHORUS PESTICIDES IN THE PELOTAS RIVER SEDIMENT
ABSTRACT Aquatic sediments are widely used for the evaluation of anthropogenic contamination due to their ability to adsorb particles and contaminants, making them historical environmental archives. Therefore, the objective was to evaluate the contamination of the Pelotas River sediments, at the border between the states of Santa Catarina and Rio Grande do S
Eng. Agríc.. Publicado em: 2018-01
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6. Degrading Pesticides with Waste Product: Imidazole-Functionalized Rice Husk Catalyst for Organophosphate Detoxification
Rice husk (RH) is one the largest agricultural waste products worldwide, and rice is one of the crops that use the most pesticides. Among these, organophosphates have been of increasing concern due to their high toxicity. Herein, we report the functionalization of RH with imidazole groups (RHIMZ) to obtain sustainable catalysts from waste for organophosphate
J. Braz. Chem. Soc.. Publicado em: 2017-09
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7. Contrasting patterns of insecticide resistance and knockdown resistance (kdr) in Aedes aegypti populations from Jacarezinho (Brazil) after a Dengue Outbreak
ABSTRACT After a dengue outbreak, the knowledge on the extent, distribution and mechanisms of insecticide resistance is essential for successful insecticide-based dengue control interventions. Therefore, we evaluated the potential changes to insecticide resistance in natural Aedes aegypti populations to Organophosphates (OP) and Pyrethroids (PY) after chemic
Rev. Bras. entomol.. Publicado em: 2016-03
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8. Comparison and evaluation of two methods for the pesticide residue analysis of organophosphates in yerba mate
Abstract Microwave Assisted Extraction and a modified CEN-QuEChERS methodology were evaluated as extraction and clean up procedures for the simultaneous analysis of 42 organophosphate pesticides in yerba mate (Ilex paraguaiensis). The obtained extracts were analyzed by gas chromatography using a flame photometric detector. Linearity, recovery percentages, re
Rev. bras. farmacogn.. Publicado em: 2015-04
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9. Nano-Detoxification of Organophosphate Agents by PAMAM Derivatives
For the first time, the adsorption of pesticides such as azinphos-methyl and methamidophos by polyamidoamine (PAMAM) derivatives was studied. Amine groups of PAMAM (G4 and G5) were functionalized with different biomolecules such as folic acid, coumarine, arginine, lysine, and asparagine. Subsequently, the synthesized compounds were used to trap organophospha
J. Braz. Chem. Soc.. Publicado em: 2015-03
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10. Low malathion concentrations influence metabolism in Chironomus sancticaroli (Diptera, Chironomidae) in acute and chronic toxicity tests
Low malathion concentrations influence metabolism in Chironomus sancticaroli (Diptera, Chironomidae) in acute and chronic toxicity tests. Organophosphate compounds are used in agro-systems, and in programs to control pathogen vectors. Because they are continuously applied, organophosphates often reach water sources and may have an impact on aquatic life. The
Rev. Bras. entomol.. Publicado em: 2014-09
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11. Optimization of chromatographic conditions and comparison of extraction efficiencies of four different methods for determination and quantification of pesticide content in bovine milk by UFLC-MS/MS
This paper describes the optimization of a multiresidue chromatographic analysis for the identification and quantification of 20 pesticides in bovine milk, including three carbamates, a carbamate oxime, six organophosphates, two strobilurins, a pyrethroid, an oxazolidinedione, an aryloxyphenoxypropionate acid/ester, a neonicotinoid, a dicarboximide, and thre
Quím. Nova. Publicado em: 2014
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12. Fitness evaluation of two Brazilian Aedes aegypti field populations with distinct levels of resistance to the organophosphate temephos
In Brazil, decades of dengue vector control using organophosphates and pyrethroids have led to dissemination of resistance. Although these insecticides have been employed for decades against Aedes aegypti in the country, knowledge of the impact of temephos resistance on vector viability is limited. We evaluated several fitness parameters in two Brazilian Ae.
Mem. Inst. Oswaldo Cruz. Publicado em: 2012-11