Oxidaaao De Baeyer Villiger
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1. Estudos visando a sÃntese de 7-hidroxi-6,11-ciclofarnes-3(15)-EN-2-ONA
In this work we describe alternative synthetic routes toward the preparation of a new α,β-unsaturated sesquiterpene with antibacterial activity isolated from Premma oligotricha. Baeyer-Villiger oxidation of trimethyldecalone (51a) yielded the corresponding lactone intermediate (52a) which was submitted to several sulfophenyl- and hydroxymethylation
Publicado em: 2002