Photoinduced
Mostrando 1-12 de 129 artigos, teses e dissertações.
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1. Supramolecular Approach in Energy Conversion Devices
This review summarizes investigations carried out at the Laboratory of Photochemistry and Energy Conversion (LFCE) in the University of São Paulo dealing with design and characterization of ruthenium(II), rhenium(I) and iridium(III) polypyridine complexes with desired photochemical and photophysical properties in light of the development of optoelectronics
J. Braz. Chem. Soc.. Publicado em: 2020-11
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2. Where’s the Spin? A DFT Study of Mixed-Valence Cyanide-Bridged Ruthenium Polypyridines
This article discusses the use of density functional theory (DFT) calculations in classifying and characterizing bimetallic ruthenium mixed-valence systems in terms of their electronic localization/delocalization degree. A standard B3LYP/LanL2DZ methodology including integral equation formalism-polarizable continuum model (IEF-PCM) solvent model is evaluated
J. Braz. Chem. Soc.. Publicado em: 2020-11
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3. Mackie B. Corra para ser feliz: como a corrida salvou minha vida. Rio de Janeiro: Harper Collins; 2019.
This article discusses the use of density functional theory (DFT) calculations in classifying and characterizing bimetallic ruthenium mixed-valence systems in terms of their electronic localization/delocalization degree. A standard B3LYP/LanL2DZ methodology including integral equation formalism-polarizable continuum model (IEF-PCM) solvent model is evaluated
Ciênc. saúde coletiva. Publicado em: 2020-11
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4. Sunlight-Driven Dehydrogenative Oxidation Photocatalysis by a Mononuclear Complex Acting as both Chromophore and Catalyst
Under simulated solar irradiation in the visible spectral region, the catalytically active RuIV-oxo species [Ru(O)(bpy)(tppz)]2+ (tppz = tetrapyridylpyrazine, a strongly π-accepting tridentate N, N, N-ligand) is produced directly from a single metal-to-ligand charge-transfer (MLCT) photoexcitation of the resting RuII-aquo complex [Ru(H2O)(bpy)(tppz)]2+ in a
J. Braz. Chem. Soc.. Publicado em: 2020-11
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5. A Highly Selective Fluorescent Chemosensor for Al3+ Based on 2,2’:6’,2”-Terpyridine with a Salicylal Schiff Base
Two 2,2’:6’,2”-terpyridine-based Schiff bases (TPySSB and TPySB) have been synthesized. The TPySSB shows remarkable selective ‘off-on’ fluorescence for Al3+ in combination with photoinduced electron transfer (PET) mechanism and C=N isomerization mechanism. Chemosensor TPySSB binds Al3+ in a 1:2 ratio with an association constant 6.8 × 105 (correla
J. Braz. Chem. Soc.. Publicado em: 2020-09
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6. Leucine-rich glioma inactivated 3: a novel keratinocyte-derived melanogenic cytokine in vitiligo patients
Abstract: Background: In-vitro studies showed that Leucine-rich glioma inactivated 3 (LGI3) is a keratinocyte-derived cytokine that stimulates melanin synthesis and is increased after ultra violet B (UVB) irradiation. So, we postulated that LGI3 may be involved in vitiligo aetiopathogenesis and may participate in narrow band ultra violet B (NB-UVB) induced
An. Bras. Dermatol.. Publicado em: 17/10/2019
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7. Enhanced Photocatalytic Degradation Activity of BiFeO3 Microspheres by Decoration with g-C3N4 Nanoparticles
In this work, the g-C3N4 nanoparticles decorated BiFeO3 microspheres composites (g-C3N4/BiFeO3) were successfully synthesized by hydrothermal treatment of g-C3N4 nanoparticles together with BiFeO3 microspheres. The SEM and HRTEM observation indicate that the C3N4 nanoparticles with size of 30-50 nm are well decorated on the surface of BiFeO3 microspheres. Th
Mat. Res.. Publicado em: 26/07/2018
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8. Influence of the Protonatable Site in the Photo-Induced Proton-Coupled Electron Transfer between Rhenium(I) Polypyridyl Complexes and Hydroquinone
In the present work the influence of the distance of the protonatable site of different ancillary ligands to the metal center on the luminescence quenching of ReI polypyridyl complexes by hydroquinone are evaluated by means of experimental and theoretical studies. In these systems, it is expected the occurrence of proton-coupled electron transfer (PCET) reac
J. Braz. Chem. Soc.. Publicado em: 2017-09
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9. In Situ Photoactivated Plasmonic Ag3PO4@silver as a Stable Catalyst With Enhanced Photocatalytic Activity Under Visible Light
Silver orthophosphate (Ag3PO4) had been reported as an excellent candidate to split water or decompose pollutants with high efficiency in visible light region, yet is not stable due to the reduction of silver ion. In this work, an easy-fabricated method (in situ photoinduced reduction) was provided to enhance the stability of Ag3PO4 for its possible applicat
Mat. Res.. Publicado em: 03/04/2017
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10. Photo-Induced conductivity of heterojunction GaAs/Rare-Earth doped SnO2
Rare-earth doped (Eu3+ or Ce3+) thin layers of tin dioxide (SnO2) are deposited by the sol-gel-dip-coating technique, along with gallium arsenide (GaAs) films, deposited by the resistive evaporation technique. The as-built heterojunction has potential application in optoelectronic devices, because it may combine the emission from the rare-earth-doped transpa
Mat. Res.. Publicado em: 23/04/2013
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11. Photo-induced dipole relaxation current in natural Amethyst
Thermally stimulated depolarization current (TSDC) measurements were carried out for SiO2 in the amethyst form, aiming to investigate the relationship of observed current with relaxation phenomena related to quartz impurities. In addition to TSDC conventional dark procedure, photo-induced TSDC was also carried out, where the exciting light came from an Ar+ l
Materials Research. Publicado em: 31/05/2012
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12. X-ray photoinduced effects in glassy films of CuO doped [Sb(PO3)3]n-Sb2O3 system / Estudo dos efeitos fotoinduzidos por Raio-X em filmes vítreos do sistema [Sb(PO3)3]n-Sb2O3 dopados com CuO
The photosensibility to radiation of phosphate glasses is a property that has attracted great interest in the last decades12. In this work, we realized a systematic and comparative study of the photoinduced phenomena through characterization of the doped copper oxide (CuO) (Sb(PO3)3)n-Sb2O3 system films. In this study, we observed the photostructural changes
Publicado em: 2010