Poly Dimethylsiloxane
Mostrando 1-12 de 17 artigos, teses e dissertações.
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1. Per-Aqueous Liquid Chromatography for the Separation of Polar Compounds Preparation and Characterization of Poly(ethylene oxide co dimethylsiloxane) Based Stationary Phase
Poly(ethylene oxide-co-dimethylsiloxane) was thermally immobilized on silica particles-Si(PEO)-to separate small polar compounds with water-rich mobile phases. Poly(ethylene oxide-co-dimethylsiloxane) content on Si(PEO) stationary phase was optimized using a central composite design. Infrared spectroscopy, scanning electron microscopy, and thermogravimetric
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Poly(dimethylsiloxane) and Poly[vinyltrimethoxysilane-co-2-(dimethylamino)ethyl methacrylate] Based Cross-Linked Organic-Inorganic Hybrid Adsorbent for Copper(II) Removal from Aqueous Solutions
An organic-inorganic hybrid adsorbent was prepared and its application for the uptake of CuII ions from aqueous solutions was studied. The polymer network was composed of poly(dimethylsiloxane) (PDMS), vinyltrimethoxysilane (VTMS), and 2-(dimethylamino)ethyl methacrylate (DMAEMA), described as PDMS-net-P(VTMS-co-DMAEMA). The chemical groups, thermal stabilit
J. Braz. Chem. Soc.. Publicado em: 2016-12
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3. Synthesis of Poly(Dimethylsiloxane) Networks Functionalized with Imidazole or Benzimidazole for Copper(II) Removal from Water
Functionalized elastomeric networks were obtained via a polycondensation reaction between poly(dimethylsiloxane) (PDMS) containing Si(CH3)2OH as end groups and an imidazole- or benzimidazole-modified alkoxysilane. The structure of the polymeric materials was characterized via attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and
J. Braz. Chem. Soc.. Publicado em: 2015-02
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4. NOVO SORVENTE DE HIDROFOBICIDADE REDUZIDA PARA EXTRAÇÃO EM FASE SÓLIDA: PREPARAÇÃO E CARACTERIZAÇÃO
C18 chemically bonded sorbents have been the main materials used in solid phase extraction (SPE). However, due their high hydrophobicity some hydrophobic solutes are strongly retained leading to the consumption of larger quantities of organic solvent for efficient recoveries. This work presents a sorbent with lower hydrophobicity but similar selectivity to t
Quím. Nova. Publicado em: 2015-02
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5. Preparo, caracterização e aplicação de fases estacionárias de poli(dimetilsiloxano-co-metilfenilsiloxano) sorvidas e imobilizadas sobre sílica e sílica zirconizada / Preparation, characterization and application of stationary phases based on poly(dimethylsiloxane-co-methylphenylsiloxane), sorbed and immobilized onto silica and zirconized silica
This work describes the development of new stationary phases (SP) based on poly(dimethylsiloxane-co-methylphenylsiloxane) sorbed and immobilized onto silica and zirconized silica for reversed phase high performance liquid chromatography. The polymer was immobilized by thermal treatment at 140 °C during 6 h, which were the conditions that produced SP with th
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 25/02/2011
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6. Metalloporphyrins and salen complexes as a P450 biomimetic model for the metabolism of antiepileptic and antidepressant drugs / Metaloporfirinas e compostos salen como modelos biomiméticos do citocromo P450 no metabolismo de fármacos anticonvulsivante e antidepressivo
In this work, the catalytic activities of metalloporphyrins and the salen complex (Jacobsen catalyst) in solution and immobilized on different supports were studied in the oxidation of hydrocarbons, anticonvulsivant drugs (carbamazepine and primidone) and antidepressives (fluoxetine) by the following oxygen donors: hydrogen peroxide, terc-butyl hydroperoxide
Publicado em: 2008
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7. Detecção condutométrica sem contato: uma nova ferramenta para monitoramento de interações biomoleculares em microssistemas analíticos / Contactless conductivity detection: a new tool for monitoring biomolecular interactions on analytical microsystems
The study reported in this thesis shows the application of a capacitively coupled contactless conductivity detection (C4D) for monitoring biomolecular interactions on analytical microsystems. Initially, the analytical performance of the microsystems fabricated in glass, poly(dimethylsiloxane) (PDMS) and polyester-toner (PT) was investigated in order to choos
Publicado em: 2008
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8. Preparação de fases estacionarias para CLAE com uma mistura de poli(dimetilsiloxano) e poli(metiloctadecilsiloxano) sorvidos e imobilizados por tratamento termico sobre silica / Synthesis of stationary phases for HPLC with a poly(dimethylsiloxane) - poly(methyloctadecylsiloxane) mixture sorbed and immobilized by thermal tratment onto silica
In this work the conditions for the preparation of a stationary phase of use in reverse phase high performance liquid cromatography (RP-HPLC) with a mixture of poly(dimethylsiloxane) (PDMS) and poly(methyloctadecilsiloxane) (PMODS) sorbed and immobilized by thermal treatment (in an inert atmosphere) on Kromasil silica (spherical, 5 mm) were optimized. The st
Publicado em: 2007
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9. Preparação de redes modificadas de poli(dimetilsiloxano) com ion piridinio ou etilenodiamina : estudo da adsorção de ions metalicos em etanolico / Preparation of modified poly(dimethylsiloxane) network with pyridine ion or ethylenediamine : study of metalic ion adsoption from ethanol solution
In this work elastomeric polymeric networks based on poly(dimethilsiloxane) PDMS, modified with pyridine ion or ethylenediamine, were prepared. These materials were characterized by infrared spectrometry, thermogravimetric analysis, differential scanning calorimetry and nuclear magnetic resonance (NMR) of Si and C. The results showed that both materials pres
Publicado em: 2007
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10. Separation of binary mixtures by pervaporation and reverse osmosis / Separação de misturas binarias por pervaporação e osmose inversa
In this work, the modelling and simulation of pervaporation and reverse osmosis processes for binary mixtures were carried out. The development of prediction methodologies for process variables of pervaporation and reverse osmosis without the necessity of experimental data was the general guideline followed; the experimental data used in these methodologies
Publicado em: 2007
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11. Obtenção e caracterização de materiais hibridos organo-inorganicos a base de silsesquioxanos em ponte
In this work, organic-inorganic hybrid materiaIs were prepared through an organic component and an alkoxysilane properly functionalized, by the sol-gel process, at room temperature. Dibutyltin dilaurate was used as catalyst of the silane s hydrolyze/condensation reactions. These materiaIs were obtained from the stechiometric mixture of epoxy resin poly(bisph
Publicado em: 2001
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12. Resinas de silicona a base de silsesquioxanos: síntese, estudo estrutural, morfológico e avaliação do comportamento térmico
In the present work the synthesis, structure, morphology and thermal behaviour of silicone resins prepared from phenyltrichlorosilane, phenyltriethoxysilane, n-octyltriethoxysilane or n-dodecyltriethoxysilane, as sources of T units, and poly(dimethylsiloxane) or 1,3-diethoxytetramethyldisiloxane, as sources of D units were investigated. Two series of resins
Publicado em: 2001