Proton Activity
Mostrando 1-12 de 582 artigos, teses e dissertações.
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1. The Influence of the Platinum Weight Percentage in the Catalyst Formulation on the Performance of a High Temperature Ethanol Electroreformer Based on H3PO4 Doped Polybenzimidazole for Green Hydrogen Production
A vapor-fed high temperature proton exchange ethanol electroreformer has been developed based on the use of a H3PO4-doped polybenzimidazole membrane to produce green hydrogen. As a key parameter, this article describes the influence of platinum weight percent (wt.%) in the catalyst formulation from different commercial catalysts (20, 40, 60, 80 wt.% Pt/C and
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. SYNTHESIS, ELECTRONIC AND SPECTRAL PROPERTIES OF NEW 1,3,4-THIADIAZOLE COMPOUNDS AND THE SPECTRAL ANALYSIS OF THEIR CONFORMERS USING DENSITY FUNCTIONAL THEORY
In this study, new 1,3,4-thiadiazole compounds were synthesised and characterised by FT-IR, 1H-NMR, UV-vis spectroscopy and elemental analysis, Furthermore, the relationship between the electronic and spectral data of the 16 conformers of each compound was investigated by theoretical calculations; the theoretical data were compared with the experimental resu
Quím. Nova. Publicado em: 2019-02
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3. CO Tolerance and Stability of Proton Exchange Membrane Fuel Cells with Nafion® and Aquivion® Membranes and Mo-Based Anode Electrocatalysts
This work presents a CO tolerance study of PtMo/C (70:30, Pt:Mo) and Pt/MoO2-C anode catalysts on proton exchange membrane fuel cells (PEMFC) with Nafion® and Aquivion® ionomer membranes. Results denote improved activity for the hydrogen oxidation reaction (HOR) in the presence of CO on both anode catalysts at 85 ºC. Experiments of identical location tran
J. Braz. Chem. Soc.. Publicado em: 2018-05
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4. Activity and Stability of Dispersed Multi Metallic Pt-based Catalysts for CO Tolerance in Proton Exchange Membrane Fuel Cell Anodes
ABSTRACT Studies aiming at improving the activity and stability of dispersed W and Mo containing Pt catalysts for the CO tolerance in proton exchange membrane fuel cell (PEMFC) anodes are revised for the following catalyst systems: (1) a carbon supported PtMo electrocatalyst submitted to heat treatments; (2) Pt and PtMo nanoparticles deposited on carbon-supp
An. Acad. Bras. Ciênc.. Publicado em: 16/04/2018
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5. Antioxidant activity, antibacterial potential and characterization of active fraction of Dioscorea pentaphylla L. tuber extract collected from Similipal Biosphere Reserve, Odisha, India
ABSTRACT Dioscorea pentaphylla L., a wild tuber is used both as food and medicines among different ethnic groups of Similipal Biosphere Reserve, India. Tubers are used against skin infections. In order to establish and confirm tribal claims, methanol extract was subjected to fractionation. The active fraction (DP1) was subsequently used for further purificat
Braz. J. Pharm. Sci.. Publicado em: 09/04/2018
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6. Solid-Phase Peptide Synthesis of Dipeptide (Histidine-β-Alanine) as a Chelating Agent by Using Trityl Chloride Resin, for Removal of Al3+, Cu2+, Hg2+ and Pb2+: Experimental and Theoretical Study
Solid-phase peptide synthesis of dipeptide (histidine-β-alanine) as a chelating agent examined by common N-9-fluorenylmethyloxycarbonyl-N-trityl-L-histidine and tert-butyloxycarbonyl-β-alanine-OH amino acid derivatives. Trityl chloride resin was used as a carrier resin. The molecular structure of the dipeptide was definite by using different methods such a
J. Braz. Chem. Soc.. Publicado em: 2016-10
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7. Preparation of Two Maleic Acid Sulfonamide Salts and Their Copper(II) Complexes and Antiglaucoma Activity Studies
Two novel proton transfer compounds (HAP)+(SAMAL)- and (HBI)+(SAMAL)-.H2O were obtained from (E)-4-oxo-4-(4-sulfamoylphenylamino)but-2-enoic acid (HSAMAL) and 2-aminopyridine (AP) or 1H-benzimidazole (BI), respectively. Copper(II) complexes of salts and of HSAMAL have also been prepared. They have been characterized by elemental, spectral, thermal analyses,
J. Braz. Chem. Soc.. Publicado em: 2016-10
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8. Plant proton pumps as markers of biostimulant action
ABSTRACT A standard protocol to evaluate the effects of biostimulants on plant physiology is still lacking. The proton pumps present in the vacuolar and plasma membranes are the primary agents responsible for the regulation of the electrochemical gradient that energizes the nutrient uptake system and acid growth mechanism of plant cells. In this study, two o
Sci. agric. (Piracicaba, Braz.). Publicado em: 2016-02
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9. SYNTHESIS AND BIOLOGICAL ACTIVITY OF NEW SERIES OF ORGANOTIN(IV) ESTERS WITH N,N-DIACETYLGLYCINE
A bioactive N,N-diacetylglycine (NNDAG) and new organotin(IV) complexes (OTCs) (1-7) were synthesized. Spectroscopic techniques were employed to characterize NNDAG and OTCs. FTIR was employed to verify N,N protection of glycine by acetyl groups. The disappearance of υ(OH) at 3000-2600 cm-1 showed de-protonation of free ligand. The Δυ 150<200 cm-1 of OTCs
Quím. Nova. Publicado em: 2016-01
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10. Recombinogenic activity of Pantoprazole® in somatic cells of Drosophila melanogaster
Pantoprazole® is one of the leading proton pump inhibitors (PPIs) used in the treatment of a variety of diseases related to the upper gastrointestinal tract. However, studies have shown an increased risk of developing gastric cancer, intestinal metaplasia and hyperplasia of endocrine cells with prolonged use. In the present study, the somatic mutation and r
Genet. Mol. Biol.. Publicado em: 2015-03
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11. Heparinases: Clonagem, Expressão e Requisitos Estruturais para a Atividade. / Heparinases: Cloning, Expression and Structural Requirements for Activity.
Características estruturais de heparina (Hep) e heparam sulfato (HS) têm sido determinadas usando enzima de Flavobacterium heparinum, uma bactéria de solo, não-patogênica. Sob indução com Hep/HS ou seus dissacarídeos como única fonte de carbono e nitrogênio, a bactéria sintetiza heparinase e heparitinases I e II. Essas liases clivam heparina e HS
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 27/04/2011
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12. Gastroprotective effects of essential oil from Protium heptaphyllum on experimental gastric ulcer models in rats
Peptic ulcers are a common disorder of the entire gastrointestinal tract, its etiology has not been completely elucidated. The basic physiopathological of peptic ulcers result from an imbalance between some endogenous aggressive factor and cytoprotective factors. The treatment of this disease is usually done with antacids or proton pump, but are currently be
Revista Brasileira de Farmacognosia. Publicado em: 08/07/2011