Prussian Blue
Mostrando 1-12 de 31 artigos, teses e dissertações.
-
1. Performance of Water Oxidation by 3D Printed Electrodes Modified by Prussian Blue Analogues
The water oxidation is the limiting step in the water-splitting process. Given this scenario, the development of new catalysts is essential in this field. The emergent demand is the use of Earth-abundant elements and catalysts with high performance under mild conditions. Because of this, catalysts such as Prussian Blue analogues (PBA) have been receiving a l
J. Braz. Chem. Soc.. Publicado em: 2020-11
-
2. Tear down academic paywall during pandemic
Zinc hexacyanoferrate (ZnHCF) is a Prussian Blue analog and can be intercalated by both monovalent and divalent ions. ZnHCF/multi-walled carbon nanotube (MWCNT) film could be used as a cathode for zinc ions battery. Carbon nanotubes improved significantly the electrochemical performance of the electrode. It is described the preparation of ZnHCF/MWCNT films b
Braz. J. Biol.. Publicado em: 2020-09
-
3. Zinc Hexacyanoferrate/Multi-Walled Carbon Nanotubes Films for Rechargeable Aqueous Batteries
Zinc hexacyanoferrate (ZnHCF) is a Prussian Blue analog and can be intercalated by both monovalent and divalent ions. ZnHCF/multi-walled carbon nanotube (MWCNT) film could be used as a cathode for zinc ions battery. Carbon nanotubes improved significantly the electrochemical performance of the electrode. It is described the preparation of ZnHCF/MWCNT films b
J. Braz. Chem. Soc.. Publicado em: 2020-09
-
4. Drawing Electrochemical Sensors Using a 3D Printing Pen
This communication demonstrates that a 3D printing pen, commercially-available as a toy for kids, can be used to draw thermoplastic electrochemical sensors using conductive filaments over any desirable format and substrate. A polylactic acid filament containing graphene or carbon black was passed through the 3D pen that works as a handheld 3D printer (fused
J. Braz. Chem. Soc.. Publicado em: 2020-09
-
5. RAMAN STUDIES OF BIS(PHENYLTERPYRAZINE)IRON(II) AND SUPRAMOLECULAR SPECIES WITH PENTACYANIDOFERRATE(II) IONS
The chemistry and spectroscopy of the iron(II) phenylterpyrazine complex, [Fe(phtpz)2]2+, were investigated in comparison with the analogous phenylterpyridine species, Fe(phtpy)2]2+, and the results indicated a strong electronic delocalization on the Fe(II) terimine chromophore encompassing the lateral pyrazyl groups. The delocalized nature of the molecular
Quím. Nova. Publicado em: 05/12/2019
-
6. Ocotea nutans (Nees) Mez (Lauraceae): chemical composition, antioxidant capacity and biological properties of essential oil
The present study was undertaken to assess the potential uses of the essential oil obtained from Ocotea nutans (Nees) Mez. The hydrodistilled essential oil from O. nutans leaves was analyzed by gas chromatography-mass spectrometry. Fifty-eight compounds representing 87,29% of the total leaf essential oil components were identified, of which biciclogermacrene
Braz. J. Pharm. Sci.. Publicado em: 12/08/2019
-
7. Exploring the metallochromic behavior of pentacyanidoferrates in visual, electronic and Raman spot tests
Abstract: Pentacyanidoferrate(II) complexes of aromatic N-heterocycles, such as 4-cyanopyridine, exhibit characteristic colors and strong metallochromism associated with the donor-acceptor interactions of the metal ions with the cyanide ligands. In the presence of transition metal ions insoluble polymeric complexes are formed, displaying bright yellow, red,
An. Acad. Bras. Ciênc.. Publicado em: 25/04/2019
-
8. Electrodeposition of Prussian Blue/Carbon Nanotube Composites at a Liquid-Liquid Interface
The iron complex hexacyanoferrate (Fe4[Fe(CN)6]3), known as Prussian Blue (PB), was electrodeposited over a free-standing carbon nanotube (CNT) film assembled at the interface between two immiscible liquids, water and 1,2-dichlorobenzene. Polarization of the interface achieved through a fixed potential or under potential variation enabled iron present inside
J. Braz. Chem. Soc.. Publicado em: 2018-05
-
9. Selective Determination of Unsymmetrical Dimethylhydrazine on a Prussian Blue Modified Carbon Paste Electrode
The electrocatalytic oxidation of unsymmetrical dimethylhydrazine (UDMH) has been studied on a Prussian Blue modified carbon paste electrode (PBMCPE) by cyclic voltammetry technique. The results show that Prussian Blue acts as a suitable modifier for electron transfer in the oxidation of UDMH. A linear range of 3 × 10-5 to 1.15 × 10-3 mol L-1, with a limit
J. Braz. Chem. Soc.. Publicado em: 2015-03
-
10. SÍNTESE E CARACTERIZAÇÃO DE COMPÓSITOS ORGÂNICO-INORGÂNICOS MACROPOROSOS PARA O SENSORIAMENTO DE H2O2
Electrodes modified with poly(5-amino-1-naphthol)/Prussian blue (poly(5-NH2-1-NAP)/PB) hybrid films are able to electrochemically reduce H2O2 in medium containing an excess of Na+ cations. This is an important advantage for biosensing applications over electrodes in which only conventionally (electro) deposited Prussian blue is present. Consequently, the aim
Quím. Nova. Publicado em: 2015-02
-
11. Caracterizações e aplicações analíticas de eletrodos compósitos modificados com Azul da Prússia e determinações simultâneas em sistemas de análise por injeção em batelada empregando somente um eletrodo de trabalho
Esta tese apresenta algumas potencialidades dos sistemas de análise por injeção em fluxo (FIA) e análise por injeção em batelada (BIA) acopladas à detecção amperométrica para o desenvolvimento de métodos de rotina úteis em alguns setores industriais, como o alimentício, farmacêutico e de biocombustíveis. Nesta perspectiva, foi empregado um ele
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 06/06/2012
-
12. Um exemplo de aplicação da Microscopia Raman na autenticação de obras de arte
In the present work, Raman Microscopy was employed in the characterization of the pigments used in a drawing assigned to Tarsila do Amaral, one of the most important Brazilian artists. The work (colored pencil on paper), supposedly produced in the 1920 decade, is of a very simple composition, where blue, green and brown were the colors used. Prussian Blue wa
Química Nova. Publicado em: 2011