Sers
Mostrando 1-12 de 63 artigos, teses e dissertações.
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1. NANOMATERIAIS PLASMÔNICOS: PARTE II. QUÍMICA DE COORDENAÇÃO DE SUPERFÍCIE E SUA APLICAÇÃO EM SENSORES E CATALISADORES
In this second part we will discuss how surface chemistry properties of plasmonic nanomaterials can be tailored by applying coordination chemistry, supramolecular and materials chemistry approaches, in which nanoparticles with well-controlled features conjugated with properly chosen molecules are the basis of functional organized structures that can be appli
Quím. Nova. Publicado em: 2020-12
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2. NANOMATERIAIS PLASMÔNICOS: PARTE I. FUNDAMENTOS DA ESPECTROSCOPIA DE NANOPARTÍCULAS E SUA RELAÇÃO COM O EFEITO SERS
We perform an analysis of plasmonic nanomaterials in a two part review, the first of which constitutes the present work. Here, attention is given to the fundamentals of metal nanoparticle optical properties. It is discussed the principles regarding the excitation of localized surface plasmon modes in nanostructures of different sizes, shapes and surrounding
Quím. Nova. Publicado em: 2020-12
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3. DETECTION OF THE PEPTIDE P17-1 (HIV) BY SURFACE ENHANCE RAMAN SCATTERING (SERS)
A bioanalytical method for HIV detection based on surface-enhanced Raman scattering (SERS) is described. The assay targeted the peptide p17-1. This peptide sequence is present in the protein p17, a structural protein essential in the life cycle of the human immunodeficiency retrovirus (HIV). The antibody anti-p17 was immobilized in a planar gold surface usin
Quím. Nova. Publicado em: 05/12/2019
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4. BIOSSENSORES PLASMÔNICOS BASEADOS EM ESPALHAMENTO RAMAN INTENSIFICADO POR SUPERFÍCIE UTILIZANDO NANOBASTÕES DE OURO
There is still a significant need for low cost, fast and trustworthy diagnostic devices based on biosensors, which may impact positively for applications in developing countries. Localized surface plasmon resonance (LSPR) based biosensors have been taken as powerful alternative to deal with the above limitations. The local electromagnetic field enhancement c
Quím. Nova. Publicado em: 05/12/2019
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5. CORRELATING SINGLE-MOLECULE SERS STATISTICS TO PLASMONIC NANOCLUSTER STRUCTURE AND NEAR-FIELD PROPERTIES
Near-field properties due to surface plasmon excitation is a key element for different applications of metal nanoparticles, such as surface-enhanced Raman scattering (SERS). Therefore, a characterization of such properties is fundamental for the correct interpretation of experimental results, such as the strong fluctuation of intensities observed at low anal
Quím. Nova. Publicado em: 05/12/2019
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6. HOTSPOT STABILIZATION OF GOLD NANOPARTICLES FOR APPLICATION OF QUANTITATIVE SERS IN BIOANALYTICAL SYSTEMS
A complete procedure including synthesizing gold nanoparticles and further hotspots stabilization is presented. Colloidal gold synthesis followed a citrate reducing reaction, then, an ideal condition for SERS enhancement with quantitative purposes was reached by searching equilibrium between salt- and analyte-induced aggregation. Under this condition, a mild
Quím. Nova. Publicado em: 05/12/2019
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7. NANOESPECTROSCOPIA DE ABSORÇÃO DE RADIAÇÃO SÍNCROTRON NO INFRAVERMELHO PARA NANOESPECIAÇÃO DE PRODUTOS DE CORROSÃO METÁLICA
The understanding of chemical and physical behavior of materials, especially metals and their alloys, is of utmost importance for industrial and technological applications, development of new materials and preservation of cultural heritage. The use of complementary analytical techniques has allowed a better understanding of corrosion mechanisms, and results
Quím. Nova. Publicado em: 05/12/2019
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8. Interplay between Near-Field Properties and Au Nanorod Cluster Structure: Extending Hot Spots for Surface-Enhanced Raman Scattering
Materials science has observed a continuous increase in the use of metal nanoparticles in a wide range of studies, from fundamental physics to technological applications such as photocatalysis and optical communication devices. This broad scope has the same fundamental origin, the localized surface plasmons, whose excitation leads to strong light confinement
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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9. New trends in plasmonic (bio)sensing
Abstract The strong enhancement and localization of electromagnetic field in plasmonic systems have found applications in many areas, which include sensing and biosensing. In this paper, an overview will be provided of the use of plasmonic phenomena in sensors and biosensors with emphasis on two main topics. The first is related to possible ways to enhance t
An. Acad. Bras. Ciênc.. Publicado em: 2018
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10. Facial Synthesis of Carrageenan/Reduced Graphene Oxide/Ag Composite as Efficient SERS Platform
In this paper, we reported the preparation of carrageenan/reduced graphene oxide/Ag composite (CA-RGO-Ag) by a wet chemical method at room temperature using carrageenan, graphene oxide and silver nitrate as starting materials. As-prepared composite was characterized by UV-vis spectroscopy, Raman spectroscopy, FTIR, SEM, EDX and XRD. Results showed that the r
Mat. Res.. Publicado em: 16/11/2016
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11. Intercalated 4-Aminobenzenethiol between Au and Ag Nanoparticles: Effects of Concentration and Nanoparticles Neighborhood on its SERS Response
In this work is reported the investigation of the 4-aminobenzenethiol (4-ABT) surface-enhanced Raman scattering (SERS) response for different 4-ABT concentrations as well as when this molecule is intercalated between Ag and Au nanoparticles (AgNP and AuNP). SERS substrates consisting of the individual AgNP or AuNP and bi-layer AgNP/4-ABT/AuNP or AuNP/4-ABT/A
J. Braz. Chem. Soc.. Publicado em: 2015-05
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12. Interação de aminoácidos e bases de ácidos nucléicos com minerais : um estudo de química prebiótica
Nessa tese foi realizado um estudo de Química Prebiótica, na qual o objetivo é entender como surgiu à vida na Terra. O estudo foi conduzido a partir da hipótese de Bernal, de que, minerais podem ter desempenhado um papel de proteção contra degradação por hidrolise ou radiação ultravioleta, das moléculas orgânicas ou mesmo como catalisadores na f
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 13/08/2012