Artigos científicos, teses e dissertações
Publicados nas melhores instituições de ensino

Estruturas HÃbridas de Nanotubos de Carbono de Parede Simples e TelÃrio. / Single Wall Carbon Nanotubes and Tellurium Hybrid Structures

In this work we use Raman spectroscopy and electron microscopy to characterize hybrid carbon nanotube single-wall and tellurium nanostructures. Carbon nanotubes are important nanostructures due to their electrical, optical and mechanical properties, which makes them attractive fo...

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X-Ray Diffraction Studies on Metal Deposition in Group D Streptococci

Tucker, Fayne L. (University of Southern California, Los Angeles), John W. Thomas, Milo D. Appleman, Stewart H. Goodman, and Jerry Donohue. X-ray diffraction studies on metal deposition in group D streptococci. J. Bacteriol. 92:1311–1314. 1966.—Streptococcus faecalis N83 and S. f...

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Association of tellurium resistance and bacteriophage inhibition conferred by R plasmids.

Concomitant resistance to tellurium compounds (Ter) and inhibition of coli-phage development (Phi) are properties mediated by many H2 incompatibility group R plasmids which have been isolated from diverse bacterial and geographic sources. Ter plasmids from tellurium-resistant bac...

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Occupational absorption of tellurium: a report of two cases.

Industrial uses of tellurium are limited, and reported cases of tellurium absorption of occupational origin are rare. Two such cases are reported here. Both showed typical signs and symptoms of intoxication; in particular, the stench of sour garlic was noted on breath and from ex...

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COMPLETE REDUCTION OF TELLURITE TO PURE TELLURIUM METAL BY MICROORGANISMS

Tucker, Fayne L. (University of Southern California, Los Angeles), John F. Walper, Milo Don Appleman, and Jerry Donohue. Complete reduction of tellurite to pure tellurium metal by microorganisms. J. Bacteriol. 83:1313–1314. 1962—The black precipitate produced in the presence of p...

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Novos aspectos e aplicações da química de teluranas e de teluretos orgânicos / New aspects and applications of the chemistry of organotelluranes and organic tellurides

The first part of this thesis deals with the study of the reactivity of electrophilic tellurium compounds, mainly tellurium tetrachloride and aromatic tellurium trichlorides. New aspects of the reactivity of TeCl4 towards alkynes and some acetophenones were disclosed. A mechanist...

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Dimethylselenide and Dimethyltelluride Formation by a Strain of Penicillium

A strain of Penicillium which produced dimethylselenide from inorganic selenium compounds was isolated from raw sewage. Sulfate and methionine enhanced growth of the fungus and its production of dimethylselenide in media containing selenite. In solutions containing selenate, meth...

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Mecanistic Studies of Reactions involving Tellurium Compounds and Synthetic Application of Chalcogenide Compounds / Estudo de mecanismos de reações envolvendo compostos de telúrio e aplicações sintéticas de compostos calcogenados

The first experimental evidence for the formation of an organic tellurium-centered radical (RTe center dot, R = Ph or nBu groups) during the hydrotelluration of alkenes and alkynes is provided. The radicals were detected by electronic paramagnetic ressonance (EPR), using DBNBS (3...

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REDUCTION OF INORGANIC COMPOUNDS WITH MOLECULAR HYDROGEN BY MICROCOCCUS LACTILYTICUS I. : Stoichiometry with Compounds of Arsenic, Selenium, Tellurium, Transition and Other Elements

Woolfolk, C. A. (University of Washington, Seattle) and H. R. Whiteley. Reduction of inorganic compounds with molecular hydrogen by Micrococcus lactilyticus. I. Stoichiometry with compounds of arsenic, selenium, tellurium, transition and other elements. J. Bacteriol. 84:647–658. ...

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Facile Synthesis of Tellurium Nanowires and Study of Their Third-Order Nonlinear Optical Properties

We report on the synthesis of single-crystalline tellurium nanowires with different aspect-ratios prepared via facile surfactant-assisted synthesis under mild conditions. Short and long Te nanowires were synthesized by the reduction of tellurium dioxide by hypophosphorous acid wi...

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Plasmid-determined resistance to tellurium compounds.

Transferable plasmids in gram-negative bacteria that confer resistance to potassium tellurite or tellurate were found. This re-istance was distinct from resistance to mercury, silver, or arsenic compounds and was unrelated to antibiotic resistance. In Escherichia coli, plasmids d...

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Síntese, Reatividade e Caracterização Estrutural de Haletos de Telúrio e Ariltelurenila com Estados de Oxidação Incomuns ou Mistos. / Synthesis, Reactivity and Structural Characterization of Tellurium and Aryltellurenyl Halides with Unusual or Mixed Oxidation States.

This work presents a study related to the halogenation of diarylditellurides (RTe)2 in order to obtain tellurium and aryltellurenyl halides with unusual or mixed oxidation states. Although regarded as essentially unstable, the aryltellurenyl monohalides (RTeX) were generated in s...

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Selenium and tellurium chemistry: historical background

Neste artigo apresentamos um apanhado geral sobre a história da química do selênio e do telúrio no Brasil e no mundo...

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Aerobic, Selenium-Utilizing Bacillus Isolated from Seeds of Astragalus crotalariae

Bacillus sp. strain SS, an aerobic, gram-positive sporeformer, was isolated from seeds of Astragalus crotalariae, a selenium-accumulating plant. This bacillus grew in a nutrient broth (containing beef extract and peptone) if the medium was supplemented with high concentrations of...

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Novas especíes aniônicas do telúrio (IV) / New anionic species of tellurium

Como extensão de um trabalho recentemente iniciado em nosso laboratório, foram preparados tetrahalogenoarilteluratos (IV) de amônio, sulfônio, selenônio, arsônio e iodônio. Os compostos foram obtidos tratando-se os trihaletos de ariltelúrio com haletos de amônio, sulfônio, selenô...

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Synthesis and crystal structures of new complex salts containing both cationic and anionic tellurium(IV) species: the role of secondary bonds in the arrangement of tellurium based tectons

Neste trabalho divulgamos a síntese e a estrutura cristalina de uma série de três novos complexos de telúrio(IV), [Te(C6H5)(CH3)2]][TeX 4(C6H5 )], X = Cl (1), Br (2) ou I (3). Nesses complexos, as ligações secundárias promovem diferentes arranjos estruturais, mostrando o caráter ...

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Effects of Te additions and stirring in the In segregation in Ga1-xInxSb alloys

Abstract The influence of tellurium in the indium segregation of Ga1-xInxSb:Te ingots obtained by the conventional vertical Bridgman method (CVBM), under stirred and non-stirred conditions, was investigated. Three Te-doped ingots and three no-doped ingots were unidirectionally so...

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TOXICOLOGIA E FARMACOLOGIA IN VITRO DE NOVOS COMPOSTOS ORGÂNICOS DE SELÊNIO E TELÚRIO COM ATIVIDADE TIPO TIOL PEROXIDASE / TOXICOLOGY AND PHARMACOLOGY OF NEW SELENIUM AND TELLURIUM ORGANIC COMPOUNDS IN VITRO WITH THIOL PEROXIDASE ACTIVITY

Glutathione peroxidase (GPx; EC 1.11.1.9) is a well-known selenoenzyme that catalyzes the reduction of hydrogen peroxide and some organic hydroperoxides by glutathione (GSH) and protects lipid membranes and other cellular components against oxidative stress, which is related to m...

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