Transesterification And Kinetic
Mostrando 1-12 de 17 artigos, teses e dissertações.
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1. Mathematical Modeling of the Transesterification Reaction by Finite Elements: Optimization of Kinetic Parameters Using the Simplex Sequential Method
The use of biodiesel as fuel has been presented as a viable alternative in the search for renewable energies. It can be produced from the transesterification reaction of vegetable oils with methanol in the presence of sodium or potassium hydroxide as catalysts. In the present research, the transesterification reaction of soybean oil was modeled considering t
J. Braz. Chem. Soc.. Publicado em: 2020-02
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2. RE-ESTERIFICATION OF MACAUBA ACID OIL USING GLYCEROL FOR ACIDITY REDUCTION AND BIODIESEL PRODUCTION
Abstract Biodiesel production using acid oils is an important alternative for biofuel cost reduction. However, it is a huge challenge for homogeneous transesterification, the main industrial route commonly used. This paper presents macauba oil with high acidity, 43.90 w/w%, as a potential raw material for biodiesel production. The acidity was reduced to 0.8
Braz. J. Chem. Eng.. Publicado em: 09/12/2019
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3. Cr/Al Oxide as Solid Acid Catalyst to Afford Babassu Biodisel
In this work, it was described the preparation and the characterization of a solid acid catalyst obtained by the mixture of Cr/Al oxides (CRAL). The catalyst was tested in the transesterification reaction of babassu oil with 5% of free fatty acid (FFA). The results of textural and acidity characteristics of CRAL were: area (56 m2 g-1), pore size (7.0 µm), t
J. Braz. Chem. Soc.. Publicado em: 2016-03
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4. Avaliação de metodologia eletroquímica no monitoramento da conversão de óleo de girassol em biodiesel
The development of analytical procedures to evaluate transesterification process is still a challenge in biodiesel production. Then, this paper shows an electroanalytical methodology to transesterification process assessment, proposing the application of nanostructured TiO2 electrodes. The results showed, for sunflower oil - methanol reaction catalyzed by KO
Química Nova. Publicado em: 2012
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5. Experimental determination of the data kinetics of transesterification reaction of vegetable oils / Determinação experimental dos dados cineticos da reação de transesterificação de oleos vegetais
The general objective of this study was to contribute with the biodiesel production. More specifically, the purpose is to obtain experimental parameters kinetics of transesterification reaction for alcoholysis reaction of various vegetable oils produced in Brazil, such as palm oil, waste frying, coconut oil, soybean oil and castor oil, being employed various
Publicado em: 2009
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6. Análise termo-oxidativa do biodiesel de girassol (helianthus annuus) / Thermo-oxidative Analysis of Sunflower (Hellianthus annus) Biodiesel
The present work aims at investing the biodiesel obtained from the transesterification of sunflower oil by means of alkaline catalysis using 30% of ethyl alcohol, 1% KOH for each 100g of oil and (1:6) oil/alcohol molar ratio. The overall content of ethyl esters (99.72%) was determined by gas chromatography coupled to mass spectrometer, confirm the efficiency
Publicado em: 2009
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7. Evaluation of the Fluid Dynamic Properties and Kinetic Study by Pressurized Differential Scanning Calorimetry (PDSC) of Ethanolic Biodiesel Derived from Used Frying Oil / Avaliação das Propriedades Fluído-dinâmicas e Estudo Cinético por Calorimetria Exploratória Diferencial Pressurizada (PDSC) de Biodiesel Etílico Derivado de óleo de fritura usado
The present work aimed at investigating the biodiesel issuing from the transesterification of used frying oil with ethanol, via alkaline catalysis. Such investigation covers its thermo-oxidative stability during heating (thermal analysis and rheological properties) as well the kinetic profiles of the samples in the best oxidative induction time by the techni
Publicado em: 2009
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8. Produção de biodiesel a partir de óleo de coco (Cocos nucifera L
The production of biodiesel has become an important and attractive process for the production of alternative fuels. This work presents a study of the biodiesel production from coconut oil (Cocos nucifera L.), by two routes: direct transesterification using NaOH as catalyst and esterification (with H2SO4) followed by basic transesterification. The reactor was
Publicado em: 2008
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9. Simulation and cost analyses in the biodisel production using vegetable oils / Simulação e analise de custos na produção de biodisel a partir de oleos vegetais
Previous works on kinetic data of transesterification reactions of soy, palm, castor, and jatropha curcas oils were used as starting point for the simulation studies carried out in this thesis. It was found that the velocity of the castor bean oil transesterification reaction was higher than for the other oils analyzed, and an explanation for this fact was s
Publicado em: 2008
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10. Productions of ethyl esters (biodesel) from the transesterification core residual oil / Produção de esteres etilicos (biodiesel) a partir da transesterização basica de oleo residual
Biodiesel (alkyl esters) is a clean burning fuel derived from a renewable lipid feedstock such as vegetable oil or animal fat. It is biodegradable, non-inflammable, nontoxic and produce much lesser COx, sulfur dioxide and unburned hydrocarbons than petroleum-based diesel. Nowadays, due to the price of virgin oil such as soybean and canola oils, the use of lo
Publicado em: 2008
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11. OtimizaÃÃo da produÃÃo de Biodiesel
In the Semi-arid of the Northeast of Brazil biodiesel production from castor oil has been studied as a important source of employs in small agriculture. However, other oleaginous adapted to an unfavorable climate, such as cotton, oiticica and jatropha, have great potential for biodiesel production. In this work a study on alternative vegetable oils was done
Publicado em: 2007
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12. Avaliação do comportamento termoanalítico e oxidativo do biodiesel de mamona / Evaluation of the thermoanalytic and oxidative behavior of the castor biodiesel
In this work biodiesel was gotten through the transesterification reaction using the oil of castor as source of triglycerides and using the methylic route for obtaining of esters. For the characterization of biodiesel and its mixtures with mineral diesel oil, physical chemical parameters and several analytical techniques had been used, as well as: gas chroma
Publicado em: 2006